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553387

Sigma-Aldrich

2-Bromo-5-methoxybenzyl bromide

97%

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About This Item

Linear Formula:
BrC6H3(CH2Br)OCH3
CAS Number:
19614-12-1
Molecular Weight:
279.96
MDL number:
MFCD00078664
UNSPSC Code:
12352100
PubChem Substance ID:
24879325
NACRES:
NA.22

Assay

97%

mp

90-94 °C (lit.)

SMILES string

COc1ccc(Br)c(CBr)c1

InChI

1S/C8H8Br2O/c1-11-7-2-3-8(10)6(4-7)5-9/h2-4H,5H2,1H3

InChI key

MURVUTUZSUEIGI-UHFFFAOYSA-N

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Application

2-Bromo-5-methoxybenzyl bromide may be used to synthesize:
  • 4-[(2-bromo-5-methoxybenzyl)oxy]-6-methyl-2H-pyran-2-one
  • precursors required for the synthesis of pentacyclic sultams
  • 3-(benzylamino)coumarins
  • 1,3,5-tribenzylated products

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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New efficient synthesis of pyrido [2, 3-c] coumarin derivatives by palladium-catalyzed Heck cyclization.
Majumdar KC, et al.
Synthesis, 23, 3647-3652 (2007)
Intramolecular cyclization reaction-Palladium (0)-catalyzed cyclization is more effective than tin hydride mediated reaction.
Majumdar KC, et al.
Canadian Journal of Chemistry, 86(4), 325-332 (2008)
Synthesis of Polycyclic Sultams by Palladium-Catalyzed Intramolecular Cyclization.
Majumdar KC, et al.
Synthesis, 18, 3127-3135 (2009)
Palladium mediated bis-and tris-biaryl Heck coupling for the synthesis of heterocycles.
Majumdar KC, et al.
Tetrahedron Letters, 49(21), 3419-3422 (2008)

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