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262064

Sigma-Aldrich

mono-Bromoborane methyl sulfide complex solution

1.0 M in methylene chloride

Synonym(s):

Bromo(dimethyl sulfide)borane, Bromo(dimethyl sulfide)dihydroboron

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100 ML
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100 ML
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About This Item

Linear Formula:
(CH3)2S·BH2Br
CAS Number:
55652-52-3
Molecular Weight:
154.86
MDL number:
MFCD00011602
UNSPSC Code:
12352112
PubChem Substance ID:
24855856
NACRES:
NA.22

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form

liquid

Quality Level

100

reaction suitability

reagent type: reductant

concentration

1.0 M in methylene chloride

density

1.347 g/mL at 25 °C

functional group

thioether

SMILES string

BBr.CSC

InChI

1S/C2H6S.BBrH2/c1-3-2;1-2/h1-2H3;1H2

InChI key

AQRNIOMHNXJPFD-UHFFFAOYSA-N

Related Categories

Application

Reactant for:
  • Substitution reactions for synthesis of N-heterocyclic carbene boranes with boron-heteroatom bonds[1]
  • Hydroboration reactions[2]
  • Regio- and chemoselective brominative cleavage of terminal epoxides[3]

Signal Word

Danger

Hazard Statements

H225,H260,H314,H336,H351

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

EUH014

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

50.0 °F

Flash Point(C)

10 °C

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number
SHBN4367
SHBK2853
SHBG6236V
SHBD4657
06696HM

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Xaba, N.; Jaganyi, D.
Polyhedron, 28, 1145-1145 (2009)
Andrey Solovyev et al.
Journal of the American Chemical Society, 132(42), 15072-15080 (2010-10-05)
Boryl halide, carboxylate and sulfonate complexes of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (dipp-Imd-BH(2)X, X = halide or sulfonate) have been prepared from the parent borane dipp-Imd-BH(3) by (1) substitution reactions with R-X (X = halide or sulfonate), (2) reactions with electrophiles (like I(2) or
Roy, C. D.; Brown, H. C.
Australian Journal of Chemistry, 60, 139-139 (2007)

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