Skip to Content
Merck
All Photos(1)

Key Documents

731277

Sigma-Aldrich

2-Cyano-2-propyl 4-cyanobenzodithioate

98% (HPLC)

Synonym(s):

2-Cyanoprop-2-yl 4-cyanodithiobenzoate, 4-Cyanobenzenecarbodithioic acid 1-cyano-1-methylethyl ester

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C12H10N2S2
CAS Number:
Molecular Weight:
246.35
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

98% (HPLC)

form

solid

mp

122-127 °C

SMILES string

CC(C)(SC(=S)c1ccc(cc1)C#N)C#N

InChI

1S/C12H10N2S2/c1-12(2,8-14)16-11(15)10-5-3-9(7-13)4-6-10/h3-6H,1-2H3

InChI key

GLQSCQVGVPUIPC-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of methyl methacrylate and styrene monomers. Chain Transfer Agent (CTA)

Legal Information

Sold for research purposes only: See sigma-aldrich.com/raftlicense. Patents: WO98/01478; WO99/311444.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

See All

Protocols

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service