Skip to Content
Merck
All Photos(1)

Documents

726656

Sigma-Aldrich

(S)-(−)-4-Methoxy-α-methylbenzylamine

ChiPros®, produced by BASF, 99%

Synonym(s):

(S)-(−)-1-(4-Methoxyphenyl)ethylamine

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C9H13NO
CAS Number:
Molecular Weight:
151.21
Beilstein:
3196456
MDL number:
UNSPSC Code:
12352112
PubChem Substance ID:
NACRES:
NA.22

grade

produced by BASF

Quality Level

Assay

≥98.5% (GC)
99%

form

liquid

optical purity

enantiomeric excess: ≥98.5%

density

1.024 g/mL at 20 °C (lit.)

SMILES string

COc1ccc(cc1)[C@H](C)N

InChI

1S/C9H13NO/c1-7(10)8-3-5-9(11-2)6-4-8/h3-7H,10H2,1-2H3/t7-/m0/s1

InChI key

JTDGKQNNPKXKII-ZETCQYMHSA-N

Looking for similar products? Visit Product Comparison Guide

Application

(S)-(−)-4-Methoxy-α-methylbenzylamine is employed in the synthesis of S(+)-4-(1-phenylethylamino)quinazolines, as human immunoglobuline E inhibitor and haloaryl-β-amino acids. It is also used as a precursor to prepare chiral intermediate in the total synthesis of solanoeclepin A.

Legal Information

ChiPros is a registered trademark of BASF SE

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Novel Synthesis of the ABC Rings of Solanoeclepin A.
Lin Y T, et al.
Organic Letters, 16(22), 5948-5951 (2014)
The asymmetric synthesis of β-haloaryl-β-amino acid derivatives.
Bull S D, et al.
Synlett, 2000(09), 1257-1260 (2000)
S (+)-4-(1-phenylethylamino) quinazolines as inhibitors of human immunoglobuline E synthesis: potency is dictated by stereochemistry and atomic point charges at N-1.
Berger M, et al.
Journal of Medicinal Chemistry, 44(18), 3031-3038 (2001)

Articles

Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service