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Sigma-Aldrich

Ammonium hydrogen difluoride

99.999% trace metals basis

Synonym(s):

Ammonium bifluoride, Etching powder

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About This Item

Linear Formula:
NH4HF2
CAS Number:
Molecular Weight:
57.04
EC Number:
MDL number:
UNSPSC Code:
12352302
eCl@ss:
38050109
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.999% trace metals basis

form

crystalline

impurities

≤15.0 ppm Trace Metal Analysis

mp

125 °C (lit.)

SMILES string

N.F.F

InChI

1S/2FH.H3N/h2*1H;1H3

InChI key

KVBCYCWRDBDGBG-UHFFFAOYSA-N

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General description

Ammonium hydrogen difluoride is a white crystalline solid commonly used as an etchant, especially in the semiconductor industry. It has excellent selectivity in etching silicon oxides and metal silicides, making it useful in the manufacturing of semiconductors and microelectronic devices. It can also be used as a fluorinating agent.

Application

Used for the preparation of ammonium aminosilylfluorides and complex metal fluorides. Employed in a new hydrothermal synthesis of complex flourides NaHoF4 and NaEuF4; these interesting compounds have the fluorite structure and are important for solid-state lasers as well as for photoluminescence and magnetic characteristics

Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chemical Communications (Cambridge, England), 1641-1641 (1996)
Fluorination of sulfide minerals with ammonium hydrogen difluoride
N.M Laptash et al.
Journal of Fluorine Chemistry, 105, 53-58 (2000)
Acid etching as surface treatment method for luting of glass-ceramic restorations, part 1: acids, application protocol and etching effectiveness
Bajraktarova-Valjakova, et al.
Open access Macedonian journal of medical sciences, 6, 568-568 (2018)
Zeitschrift fur Anorganische und Allgemeine Chemie, 622, 1646-1646 (1996)
Xun, X. et al.
Chemistry of Materials, 9, 2966-2966 (1997)

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