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345237

Sigma-Aldrich

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

98%

Synonym(s):

PdCl2(dppe)

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About This Item

Linear Formula:
[(C6H5)2PCH2CH2P(C6H5)2]PdCl2
CAS Number:
19978-61-1
Molecular Weight:
575.74
MDL number:
MFCD00015702
UNSPSC Code:
12161600
PubChem Substance ID:
24861302
NACRES:
NA.22

Assay

98%

form

powder

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium

SMILES string

Cl[Pd]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI

1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI key

LDJXFZUGZASGIW-UHFFFAOYSA-L

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
72196LD
72096LD
17104MD
17004MD
18627LD

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Leila Tabrizi et al.
Dalton transactions (Cambridge, England : 2003), 46(41), 14164-14173 (2017-10-07)
New multinuclear gold(iii), palladium(ii) pincer complexes containing bis(diphenylphosphino) ferrocene/non-ferrocene ligands of formula [(L)Au(μ2-η2-CS3)Pd(dppf)](PF6)2, 1, and [(L)Au(μ2-η2-CS3)Pd(dppe)](PF6)2, 2 (HL = 5-methoxy-1,3-bis (1-methyl-1H-benzo[d]imidazol-2-yl)benzene, dppf = 1,1'-bis(diphenylphosphino)ferrocene, and dppe = bis(diphenylphosphino)ethane) have been synthesized and fully characterized. Both complexes are more cytotoxic to

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