936685

Grubbs Catalyst^® M102 ChemBeads

• Sinónimos: Grubbs Catalyst^® M102, Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride ChemBeads, Dichloro(benzylidene)bis(tricyclohexylphosphine)ruthenium(II) ChemBeads, Grubbs Catalyst^® 1st Generation ChemBeads, Grubbs Catalyst^® M1a (C823) ChemBeads
• Fórmula empírica (notación de Hill): C₄₃H₇₂Cl₂P₂Ru
• Número de CAS: 172222-30-9
• Peso molecular: 822.96
• Código UNSPSC: 12352103

Propiedades

• formulario: solid ()
• Nivel de calidad: 100
• composición: 4-6 wt% loading of catalyst
• idoneidad de la reacción: reagent type: catalyst; core: ruthenium; reaction type: Ring-Opening Polymerization
• mp: 153 °C (dec.)
• cadena SMILES: Cl[Ru]([P](C1CCCCC1)(C2CCCCC2)C3CCCCC3)([P](C4CCCCC4)(C5CCCCC5)C6CCCCC6)(Cl)=CC7=CC=CC=C7; C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]
• InChI: 1S/2C18H33P.C7H6.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h2*16-18H,1-15H2;1-6H;2*1H;
• Clave InChI: AULHKSXXVKDNBT-UHFFFAOYSA-N

Descripción

Descripción general

ChemBeads glass beads coated with Grubbs Catalyst^® M102.

Aplicación

First metathesis catalyst to be widely used in organic synthesis. Useful for acyclic diene metathesis polymerization (ADMET), Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, ring opening metathesis (ROM), olefin cross metathesis (CM) and ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
For larger scale uses, product also available in powdered form (579726)

Características y beneficios

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Información legal

Grubbs Catalyst 7578

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Información de seguridad

• Pictogramas: GHS02
• Palabra de señalización: Warning
• Frases de peligro: H228
• Consejos de prudencia: P210 - P240 - P241 - P280 - P370 + P378
• Clasificaciones de peligro: Flam. Sol. 2
• Código de clase de almacenamiento: 4.1B - Flammable solid hazardous materials
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable