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77253

Heptafluorobutyric anhydride

Name: Heptafluorobutyric anhydride
Brand: SIAL
Price: 248 EUR

derivatization grade (GC derivatization), LiChropur^™, ≥99.0%

Sinónimos:

HFAA, HFBA, Perfluorobutyric anhydride

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A ustedes/SKU	Disponibilidad	Precio
10 mL	Póngase en contacto con nuestro Servicio de Atención al Cliente para disponibilidad	248,00 €
10 x 1 mL	Póngase en contacto con nuestro Servicio de Atención al Cliente para disponibilidad	264,00 €
50 mL	Póngase en contacto con nuestro Servicio de Atención al Cliente para disponibilidad	972,00 €

Acerca de este artículo

Fórmula lineal:

(CF₃CF₂CF₂CO)₂O

Número CAS:

336-59-4

Peso molecular:

410.06

UNSPSC Code:

41115716

NACRES:

NA.22

PubChem Substance ID:

329767572

EC Number:

206-410-8

Beilstein/REAXYS Number:

856036

MDL number:

MFCD00000432

Assay:

≥99.0% (GC), ≥99.0%

Form:

liquid

248,00 €

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Propiedades

grade

derivatization grade (GC derivatization)

Quality Segment

100

assay

≥99.0% (GC), ≥99.0%

form

liquid

quality

LiChropur^™

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

technique(s)

gas chromatography (GC): suitable

refractive index

n20/D 1.287 (lit.)

bp

108-110 °C (lit.)

mp

−43 °C (lit.)

density

1.674 g/mL at 20 °C

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C8F14O3/c9-3(10,5(13,14)7(17,18)19)1(23)25-2(24)4(11,12)6(15,16)8(20,21)22

InChI key

UFFSXJKVKBQEHC-UHFFFAOYSA-N

Descripción

General description

Heptafluorobutyric anhydride is a perfluoroacylated acylation reagent, that forms stable, volatile derivatives with alcohols, amines, and phenols. It is majorly used to prepare electron-capturing derivatives for GC/electron capture detection. It is generally used with an acid scavenger, to help drive the reaction to completion and to prevent column damage from acidic by-products of the derivatization reaction. It is also used for the frequent testing of drugs of abuse such as, amphetamines and phencyclidine by GC-MS technique.

Application

Learn more in the Product Information

Packaging

Clear borosilicate glass, high hydrolytic resistance (Type I)

Analysis Note

Suitable for derivatization of aldosterone, digoxin, digitoxin and metabolites, estradiol, postaglandins F_1α and F_2α,3-oxo-Δ⁴-steroids, steroids and testosterone.

Other Notes

Reagent for 3-enol heptafluorobutyrate, heptafluorobutyrate, heptafluorobutyryl, 17-heptafluorobutyryl and 17-heptafluorobutyrate.

HFAA acylates amines, amino acids and other compounds. HFBA derivatives are highly volatile: used in GC separation

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

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Este artículo	394912	H1006	91719
Supelco 77253 Heptafluorobutyric anhydride	Supelco 394912 Heptafluorobutyric anhydride	Sigma-Aldrich H1006 Heptafluorobutyric anhydride	Supelco 91719 Trifluoroacetic anhydride
assay ≥99.0% (GC)	assay ≥99.0%	assay ≥98%	assay ≥99.0% (GC)
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100
reaction suitability reagent type: derivatization reagent reaction type: Acylations	reaction suitability reagent type: derivatization reagent reaction type: Acylations	reaction suitability -	reaction suitability reagent type: derivatization reagent reaction type: Acylations, reagent type: derivatization reagent reaction type: Esterifications
bp 108-110 °C (lit.)	bp 108-110 °C (lit.)	bp 108-110 °C (lit.)	bp 39.5-40 °C (lit.)
mp −43 °C (lit.)	mp −43 °C (lit.)	mp −43 °C (lit.)	mp −65 °C (lit.)
density 1.674 g/mL at 20 °C	density 1.674 g/mL at 20 °C (lit.)	density 1.674 g/mL at 20 °C (lit.)	density 1.511 g/mL at 20 °C (lit.)

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pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405

Hazard Classifications

Skin Corr. 1B

Clase de almacenamiento

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c