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Merck

33676

Supelco

BDE No 99 solution

50 μg/mL in isooctane, analytical standard

Sinónimos:

2,2′,4,4′,5-Pentabromodiphenyl ether solution, 2,2′,4,4′,5-PentaBDE, PBDE 99

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About This Item

Fórmula empírica (notación de Hill):
C12H5Br5O
Número de CAS:
Peso molecular:
564.69
Número CE:
Número MDL:
Código UNSPSC:
41116107
ID de la sustancia en PubChem:
NACRES:
NA.24

grado

analytical standard

caducidad

limited shelf life, expiry date on the label

concentración

50 μg/mL in isooctane

técnicas

HPLC: suitable
gas chromatography (GC): suitable

aplicaciones

environmental

formato

single component solution

temp. de almacenamiento

2-8°C

cadena SMILES

BrC1=C(OC2=CC(Br)=C(Br)C=C2Br)C=CC(Br)=C1

InChI

1S/C12H5Br5O/c13-6-1-2-11(9(16)3-6)18-12-5-8(15)7(14)4-10(12)17/h1-5H

Clave InChI

WHPVYXDFIXRKLN-UHFFFAOYSA-N

Descripción general

BDE No 99 is a polybrominated diphenyl ether pollutant, having low acute toxicity. It can be commercially used as a flame retardant additive in building materials, textiles, plastics, and electronic equipments.

Aplicación

BDE No 99 may be used as an analytical reference standard for the determination of the analyte in:
  • House dust samples using isotope dilution method combined with liquid chromatography coupled to negative ionization atmospheric pressure photoionization tandem mass spectrometry (LC-NI-APPI-MS/MS).
  • Adipose tissue samples using gas chromatography coupled to ion-trap mass spectrometry (GC-IT-MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Otras notas

The customer needs to make sure that the standard is homogeneous, this can be achieved by shaking, vortexing , or sonicating the ampoule before opening the ampoule. Care should be taken when opening the ampoule to avoid any injuries from the broken glass.
The standard should be transferred to a clean and appropriate vial or flask using clean pipettes or micro pipettes. The vial should be immediately capped to avoid any loss or evaporation of the solvent.
After opening the ampoule, the standard should not be stored or kept in the ampoule. To preserve the integrity of the product, the standard should be transferred to an appropriate vial that must be capped and stored according to the recommendation on the Certificate of Analysis.

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Central nervous system

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

10.4 °F

Punto de inflamabilidad (°C)

-12 °C

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Visite la Librería de documentos

Youssef Oulhote et al.
Environment international, 119, 79-88 (2018-06-26)
Prenatal exposure to polybrominated diphenyl ethers (PBDEs) has been associated with cognitive deficits and behavioral problems in children. To date, no study has examined this exposure in association with neurobehavioral development in infants younger than 12 months assessed with observational tasks.
Development of a gas chromatography/ion trap mass spectrometry based method for the quantification of polybrominated diphenyl ethers and polychlorinated biphenyls in adipose tissue.
Naert C, et al.
Rapid Communications in Mass Spectrometry, 18(19), 2317-2332 (2004)
Isotope dilution method for determination of polybrominated diphenyl ethers using liquid chromatography coupled to negative ionization atmospheric pressure photoionization tandem mass spectrometry: validation and application to house dust.
Abdallah E-A M, et al.
Analytical Chemistry, 81(17), 7460-7469 (2009)
Giusy Daniela Albano et al.
Chemosphere, 241, 125087-125087 (2019-10-18)
Brominated flame-retardant (BFRs) exposure promotes multiple adverse health outcomes involved in oxidative stress, inflammation, and tissues damage. We investigated BFR effects, known as polybrominated diphenyl ethers (PBDEs) (47, 99 and 209) in an air-liquid-interface (ALI) airway tissue derived from A549 cell
Luca Maria Chiesa et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 35(7), 1340-1355 (2018-03-14)
Demand for honey is increasing, especially if it is organic and if its nutritional properties are linked to untreated environments in order to guarantee quality for health. Sources of contamination of honey can be divided into environmental and apicultural. Therefore

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