L511838

[Ir(dtbbpy)(ppy)₂][PF₆]

Aldrich^CPR

• Fórmula empírica (notación de Hill): C₄₀H₄₀F₆IrN₄P
• Número de CAS: 676525-77-2
• Peso molecular: 913.95
• Código UNSPSC: 12352200
• ID de la sustancia en PubChem: 329817539

Propiedades

• idoneidad de la reacción: reagent type: catalyst; reaction type: C-H Activation
• cadena SMILES: CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
• InChI: 1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
• Clave InChI: DZARMRZNOUWGQE-UHFFFAOYSA-N

Descripción

Aplicación

Catalyst for the visible-light mediated formation of alpha-amino radicals, used by Nishibayashi for addition into electron-poor alkenes and imines

Visible-Light-Mediated Utilization of ·-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts

In presence of [Co(bpy)₃]²⁺, serves as photosensitizer for H₂ generation from water (water splitting).

Tricyclometalated Iridium Complexes as Highly Stable Photosensitizers for Light-Induced Hydrogen Evolution

For other Visible-Light Photocatalysts, refer to: www.aldrich.com/photocatalysis

Otras notas

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Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable