939633
Indoline-2-thione
≥-95%
Sinónimos:
2,3-Dihydro-1H-indole-2-thione
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About This Item
Fórmula empírica (notación de Hill):
C8H7NS
Número de CAS:
Peso molecular:
149.21
Número MDL:
Código UNSPSC:
12352100
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Nivel de calidad
Ensayo
≥-95%
Formulario
powder or crystals
idoneidad de la reacción
reaction type: Photocatalysis
características de los productos alternativos más sostenibles
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
color
white to yellow
categoría alternativa más sostenible
cadena SMILES
S=C1NC2=CC=CC=C2C1
InChI
InChI=1S/C8H7NS/c10-8-5-6-3-1-2-4-7(6)9-8/h1-4H,5H2,(H,9,10)
Clave InChI
IGJWTYFTQNHSEK-UHFFFAOYSA-N
Descripción general
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Aplicación
Indoline-2-thione is a indole thiolate has been used in:
- The MgI2-catalyzed nucleophilic ring opening of donor-acceptor cyclopropanes
- The synthesis of indole-fused dihydrothiopyrano scaffolds via [3+3] annulations of donor-acceptor cyclopropanes
- The preparation of 2-carboxylated thieno [2,3- b] indoles
- The synthesis of thioethers from aryl chlorides & alcohols
Características y beneficios
1-Methylindoline-2-thione is an affordable indole thiolate that is useful in general synthesis as well as the transition-metal free photocatalytic reduction of a range of strong polar C-F, C-O and C-Cl bonds.
Producto relacionado
Referencia del producto
Descripción
Precios
Código de clase de almacenamiento
11 - Combustible Solids
Clase de riesgo para el agua (WGK)
WGK 3
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Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.
Braj Gopal et al.
The Journal of organic chemistry, 88(1), 132-142 (2022-12-17)
A new methodology for the synthesis of N-haloindole-fused dihydrothiopyrano derivatives via (3 + 3)-annulation of donor-acceptor cyclopropanes (DACs) with indoline-2-thiones in the presence of Sc(OTf)3 as a Lewis acid catalyst has been developed. This protocol provides a variety of indole-fused
Pan Tang et al.
The Journal of organic chemistry, 87(16), 10890-10901 (2022-08-03)
MgI2-catalyzed nucleophilic ring-opening reactions of donor-acceptor cyclopropanes with indoline-2-thiones as easy-to-handle sulfur nucleophiles were investigated. A series of functionalized γ-indolylthio butyric acid derivatives were synthesized in good to excellent yields under mild reaction conditions. Furthermore, the thioether functionalized ring-opening products
Giacomo Mari et al.
Organic & biomolecular chemistry, 20(20), 4167-4175 (2022-05-10)
A metal-free strategy, alternative to the known complex cycloaddition reactions, towards 2-carboxylated thieno [2,3-b] indole derivatives has been successfully developed. The novel approach involves as starting materials easy accessible 1,2-diaza-1,3-dienes and indoline 2-thione and requires mild reaction conditions. Furthermore, the
Shuo Wu et al.
Journal of the American Chemical Society, 146(5), 2907-2912 (2024-01-24)
Thioethers, often found in pharmaceuticals and natural compounds, typically involve metal cross-coupling reactions, high temperatures, and the use of disagreeable thiols for their synthesis. Here we present a straightforward, thiol-free organocatalytic protocol that uses mild conditions to stitch together inexpensive
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