938777

Cesium carbonate ChemBeads

• Sinónimos: Carbonic acid dicesium ChemBeads
• Fórmula empírica (notación de Hill): Cs₂CO₃
• Peso molecular: 325.82
• Código UNSPSC: 12352100

Propiedades

• formulario: solid
• Nivel de calidad: 100
• pH: 14-16(loading of base)
• cadena SMILES: O=COO[Cs].[Cs]
• InChI: 1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
• Clave InChI: FJDQFPXHSGXQBY-UHFFFAOYSA-L

Descripción

Descripción general

Cesium carbonate is a powerful inorganic base widely used in organic synthesis. It is a potential chemoselective catalyst for the reduction of aldehydes and ketones to alcohols. It is employed as base for the Heck coupling reaction of 4-trifluoromethyl-1-chlorobenzene and aryl chlorides.

Aplicación

Cesium carbonate can be used as a base in C-C and C-N cross-coupling reactions such as Suzuki−Miyaura, Heck, and Buchwald-Hartwig amination reactions. It is also used as a base in alkylation reactions. Promotes the efficient O-alkylation of alcohols to form mixed alkyl carbonates.

For general uses, product is also available in powdered form(441902)

Características y beneficios

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

• High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
• Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
• ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Información de seguridad

• Pictogramas: GHS08,GHS05
• Palabra de señalización: Danger
• Frases de peligro: H318,H361f,H373
• Consejos de prudencia: P202 - P260 - P280 - P305 + P351 + P338 - P308 + P313 - P405
• Clasificaciones de peligro: Eye Dam. 1 - Repr. 2 - STOT RE 2 Oral
• Órganos de actuación: Kidney,Adrenal gland,Testes
• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable