86870

Cloruro de tetrabutilamonio

≥97.0% (NT)

• Sinónimos: N,N,N-tributyl-butanaminium chloride
• Fórmula lineal: [CH₃(CH₂)₃]₄NCl
• Número de CAS: 1112-67-0
• Peso molecular: 277.92
• Beilstein: 3571227
• Número CE: 214-195-7
• Número MDL: MFCD00011635
• Código UNSPSC: 12352107
• ID de la sustancia en PubChem: 57653205
• NACRES: NA.22

Propiedades

• Nivel de calidad: 200
• Análisis: ≥97.0% (NT)
• formulario: crystals
• características de los productos alternativos más sostenibles: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• impurezas: ≤1% water
• solubilidad: H₂O: 20 mg/mL, clear, colorless
• categoría alternativa más sostenible: , Aligned
• cadena SMILES: [Cl-].CCCC[N+](CCCC)(CCCC)CCCC
• InChI: 1S/C16H36N.ClH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
• Clave InChI: NHGXDBSUJJNIRV-UHFFFAOYSA-M

Descripción

Descripción general

Tetrabutylammonium chloride is a quaternary ammonium salt that is commonly used as a phase transfer catalyst as well as a source of chloride ions in organic synthesis.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Aplicación

Tetrabutylammonium chloride (TBACl) can be used as a phase transfer catalyst in the synthesis of:

• 2-Amino-4H-chromene derivatives by the condensation reaction of aldehydes, malononitrile, and α, or β-naphthol.
• Methyl esters by esterification reaction of carboxylic acids with dimethyl carbonate in the presence of K₂CO₃.

It has also been used as an initiator to synthesize 11-trifluoromethylated dibenzodiazepines via cascade radical addition/cyclization of o-isocyanodiaryl amines.

TBACl can also be used with phosphorus pentoxide for greener deoxychlorination.

Process for Producing Halogenated Heteroaryl Compounds

Información de seguridad

• Pictogramas: GHS07
• Palabra de señalización: Warning
• Frases de peligro: H315,H319
• Consejos de prudencia: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Clasificaciones de peligro: Eye Irrit. 2 - Skin Irrit. 2
• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): 235.4 °F - closed cup
• Punto de inflamabilidad (°C): 113 °C - closed cup
• Equipo de protección personal: dust mask type N95 (US), Eyeshields, Gloves