494224
Tetrabromohydroquinone
98%
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About This Item
Fórmula lineal:
C6Br4-1,4-(OH)2
Número de CAS:
Peso molecular:
425.69
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
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Ensayo
98%
mp
252-255 °C (lit.)
cadena SMILES
Oc1c(Br)c(Br)c(O)c(Br)c1Br
InChI
1S/C6H2Br4O2/c7-1-2(8)6(12)4(10)3(9)5(1)11/h11-12H
Clave InChI
DTFQULSULHRJOA-UHFFFAOYSA-N
Descripción general
Tetrabromohydroquinone (TBHQ), also known as 2,3,5,6-tetrabromohydroquinone, can be synthesized by reacting bromanil with phenyl phosphine. It crystallizes in the monoclinic space group, P21/n. The effect of C-Br group on the crystal structure of TBHQ has been investigated. Its role in causing green luminescence in Ptychodera flava has been investigated.
Aplicación
Tetrabromohydroquinone may be used in the synthesis of thermoresponsive branched oligoethylene glycol dendrimers.
Palabra de señalización
Warning
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Órganos de actuación
Respiratory system
Código de clase de almacenamiento
11 - Combustible Solids
Clase de riesgo para el agua (WGK)
WGK 3
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
Equipo de protección personal
dust mask type N95 (US), Eyeshields, Gloves
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Mona A Abdel-Rahman et al.
European journal of medicinal chemistry, 69, 848-854 (2013-10-15)
Three interesting thermoresponsive branched oligoethylene glycol dendrimers based on tetrabromohydroquinone were efficiently synthesized from tetrabromohydroquinone and three different oligoethylene glycol derivatives. By visual inspection, all these dendrimers are water-soluble at room temperature. The thermoresponsive behaviors were investigated by using UV/vis
Akira Kanakubo et al.
Luminescence : the journal of biological and chemical luminescence, 20(6), 397-400 (2005-06-21)
2,3,5,6-Tetrabromohydroquinone was isolated as a luminous substance from Ptychodera flava. This compound emitted light after addition of hydrogen peroxide under basic conditions. Since hydroquinone had no fluorescence, further investigation by spectral analysis revealed that riboflavin was the only possible light
A comparative study of the crystal structures of tetrahalogenated hydroquinones and ?-hydroquinone.
Thalladi VR, et al.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 55(6), 1005-1013 (1999)
Reaction of phenylphosphine with p-quinones.
Pudovik AN, et al.
Russian Chemical Bulletin, 27(7), 1450-1452 (1978)
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