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Merck

415952

Sigma-Aldrich

Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide

97%

Sinónimos:

(2,4,6-Trimethylbenzoyl)diphenylphosphine oxide, (Diphenylphosphoryl)(mesityl)methanone, 2,4,6-Trimethylbenzoylphenyl phosphinate

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About This Item

Fórmula lineal:
(CH3)3C6H2COP(O)(C6H5)2
Número de CAS:
Peso molecular:
348.37
Número CE:
Número MDL:
Código UNSPSC:
12162002
ID de la sustancia en PubChem:
NACRES:
NA.23

Nivel de calidad

Análisis

97%

formulario

powder

mp

88-92 °C (lit.)

cadena SMILES

Cc1cc(C)c(c(C)c1)C(=O)P(=O)(c2ccccc2)c3ccccc3

InChI

1S/C22H21O2P/c1-16-14-17(2)21(18(3)15-16)22(23)25(24,19-10-6-4-7-11-19)20-12-8-5-9-13-20/h4-15H,1-3H3

Clave InChI

VFHVQBAGLAREND-UHFFFAOYSA-N

Descripción general

Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TPO) is a monoacylphosphine oxide based photoinitiator that can be incorporated in a variety of polymeric matrixes for efficient curing and color stability of the resin.

Aplicación

TPO can be used in the photo-crosslinking of PMMA composite, which can further be used as a gate insulator in organic thin film transistors (OTFTs). It can also be used in the formation of UV curable urethane-acrylate coatings. It may also be used in the photoinduced reaction for the formation of organophosphine compounds, which potentially find their usage as ligands with metal catalysts and reagents.

Almacenamiento y estabilidad

light sensitive

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Aquatic Chronic 2 - Repr. 2 - Skin Sens. 1

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Gloves, type N95 (US)


Certificados de análisis (COA)

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Photoinduced reductive perfluoroalkylation of phosphine oxides: synthesis of P-perfluoroalkylated phosphines using TMDPO and perfluoroalkyl iodides
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Chemical Communications (Cambridge, England), 51(52), 10385-10388 (2015)
Coating performance and characteristics for UV-curable aliphatic urethane acrylate coatings containing norrish type I photoinitiators
Lee B, et al.
Journal of Coatings Technology and Research, 3(3), 221-229 (2006)
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