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404284

Sigma-Aldrich

Benzyl phenyl ether

98%

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About This Item

Fórmula lineal:
C6H5CH2OC6H5
Número de CAS:
946-80-5
Peso molecular:
184.23
Número MDL:
MFCD00020660
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
24865236
NACRES:
NA.22

Análisis

98%

bp

286-287 °C (lit.)

mp

39-41 °C (lit.)

cadena SMILES

C(Oc1ccccc1)c2ccccc2

InChI

1S/C13H12O/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13/h1-10H,11H2

Clave InChI

BOTNYLSAWDQNEX-UHFFFAOYSA-N

Descripción general

Benzyl phenyl ether is a reactive organic oxygenate, containing ether as functional group, present in subbituminous and bituminous coals. It reacts with aluminium bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.

Pictogramas

Exclamation mark
GHS07

Palabra de señalización

Warning

Frases de peligro

H315,H319,H335

Clasificaciones de peligro

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

235.4 °F - closed cup

Punto de inflamabilidad (°C)

113 °C - closed cup

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Influence of alkali carbonates on benzyl phenyl ether cleavage pathways in superheated water.
Roberts V, et al.
Applied Catalysis. B, Environmental, 95(1), 71-77 (2010)
Understanding the influence of active (zeolite) and passive (polyethylene) reaction cages on photo-Claisen rearrangements of aryl benzyl ethers.
Gu W, et al.
Langmuir, 16(17), 6977-6981 (2000)
Tibo De Saegher et al.
Materials (Basel, Switzerland), 13(3) (2020-02-09)
Monometallic cerium layered double hydroxides (Ce-LDH) supports were successfully synthesized by a homogeneous alkalization route driven by hexamethylenetetramine (HMT). The formation of the Ce-LDH was confirmed and its structural and compositional properties studied by XRD, SEM, XPS, iodometric analyses and
Catalytic decomposition of benzyl phenyl ether to aromatics over cesium-exchanged heteropolyacid catalyst.
Park HW, et al.
Korean Journal of Chemical Engineering, 28(5), 1177-1180 (2011)
Hongliang Wang et al.
ChemSusChem, 11(15), 2562-2568 (2018-07-04)
Hydrodeoxygenation of biorefinery lignin-rich wastes to jet fuel hydrocarbons offers a significant opportunity for enhancing the overall operational efficiency, carbon conversion efficiency, economic viability, and sustainability of biofuels production. However, these wastes usually mainly contain lignin with sugars, furans, and
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