283207

Magnesium bis(monoperoxyphthalate) hexahydrate

80%, technical grade

• Sinónimos: MMPP
• Fórmula lineal: (HO₂CC₆H₄CO₃)₂Mg·6H₂O
• Peso molecular: 494.64
• Número CE: 279-013-0
• Número MDL: MFCD00149614
• Código UNSPSC: 12352002
• ID de la sustancia en PubChem: 24857092
• NACRES: NA.22
• Ensayo: 80%

Propiedades

• grado: technical grade
• Nivel de calidad: 200
• Ensayo: 80%
• idoneidad de la reacción: reagent type: oxidant
• características de los productos alternativos más sostenibles: Designing Safer Chemicals; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 93 °C (dec.) (lit.)
• grupo funcional: hydroperoxide
• categoría alternativa más sostenible: Aligned,
• cadena SMILES: O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO
• InChI: 1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2
• Clave InChI: WWOYCMCZTZTIGU-UHFFFAOYSA-L

Descripción

Descripción general

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product MMPP is an alternative to widely used oxidant MCPBA as it is cheap, stable in the solid state, safer in handling and easier to use and thus aligns with the principle "Designing Safer Chemicals". For more information see the below articles.
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones.
Magnesium Bis(monoperoxyphthalate) Hexahydrate (MMPP).
Highly efficient epoxidation of unsaturated steroids using magnesium bis(monoperoxyphthalate) hexahydrate.

Aplicación

A safer, greener oxidizing reagent that is a suitable replacement for peroxycarboxylic acids and is capable of effecting many types of oxidation reactions.

Oxidation Reactions Using Magnesium Monoperphthalate: A Comparison with m-Chloroperoxybenzoic Acid

Reagent for:

• Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
• Oxidation rections under mild conditions
• Epoxidation of unsaturated steroids
• Synthesis of ring-B oxygenated steroids as anticancer agents

Información de seguridad

• Pictogramas: GHS02,GHS05,GHS07
• Palabra de señalización: Danger
• Frases de peligro: H242,H314,H332
• Consejos de prudencia: P210 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• Clasificaciones de peligro: Acute Tox. 4 Inhalation - Eye Dam. 1 - Org. Perox. E - Skin Corr. 1C
• Código de clase de almacenamiento: 5.2 - Organic peroxides and self-reacting hazardous materials
• Clase de riesgo para el agua (WGK): WGK 1
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable
• Equipo de protección personal: dust mask type N95 (US), Eyeshields, Gloves