Physical chemistry chemical physics : PCCP, 13(1), 144-148 (2010-10-30)
Magnetic properties of the TTF-CA molecular crystal below the neutral to ionic transition temperature are studied using the embedded cluster approach in combination with density functional theory. The calculated values of the Heisenberg exchange integral between the neighboring TTF and
Journal of the American Chemical Society, 133(6), 1859-1869 (2011-01-12)
The electron-transfer and hydride-transfer properties of an isolated manganese(V)−oxo complex, (TBP8Cz)Mn(V)(O) (1) (TBP8Cz = octa-tert-butylphenylcorrolazinato) were determined by spectroscopic and kinetic methods. The manganese(V)−oxo complex 1 reacts rapidly with a series of ferrocene derivatives ([Fe(C5H4Me)2], [Fe(C5HMe4)2], and ([Fe(C5Me5)2] = Fc*)
Colloids and surfaces. B, Biointerfaces, 84(1), 148-154 (2011-01-25)
An electrochemical method is described for the voltammetric determination of isoproterenol in the presence of uric acid using p-chloranil-carbon nanotubes paste electrode. Cyclic voltammetric, chronoamperometric, and electrochemical impedance spectroscopic methods have used to investigate the suitability of p-chloranil as a
Proceedings of the National Academy of Sciences of the United States of America, 109(40), 16046-16051 (2012-09-19)
Most chemiluminescence (CL) reactions usually generate only one-step CL, which is rarely dependent on the highly reactive and biologically/environmentally important hydroxyl radicals ((•)OH). Here, we show that an unprecedented two-step CL can be produced by the carcinogenic tetrachloro-1,4-benzoquinone (also known
BLT2, a low-affinity leukotriene B4 (LTB4) receptor, is a member of the G-protein coupled receptor (GPCR) family and is involved in the pathogenesis of inflammatory diseases such as asthma. Despite its clinical implications, however, no pharmacological inhibitors are available. In
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