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01713

Sigma-Aldrich

Cryolite

synthetic, ≥97.0% (from F)

Synonym(s):

Kryolith, Sodium hexafluoroaluminate

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About This Item

Linear Formula:
Na3AlF6
CAS Number:
15096-52-3
Molecular Weight:
209.94
MDL number:
MFCD00003507
UNSPSC Code:
12161600
PubChem Substance ID:
57646698
NACRES:
NA.22

Quality Level

100

Assay

≥97.0% (from F)

form

powder

quality

synthetic

reaction suitability

core: aluminum
reagent type: catalyst

impurities

≤0.5% silicic acid (as SiO2)

loss

≤0.5% loss on drying, 105 °C

cation traces

Fe: ≤500 mg/kg

storage temp.

2-30°C

SMILES string

[Na+].[Na+].[Na+].F[Al-3](F)(F)(F)(F)F

InChI

1S/Al.6FH.3Na/h;6*1H;;;/q+3;;;;;;;3*+1/p-6

InChI key

REHXRBDMVPYGJX-UHFFFAOYSA-H

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Application

Cryolite is commonly used as an electrolyte for aluminum electrolysis. Alumina is dissolved in molten cryolite is used to dissolve alumina during aluminium processing.

Signal Word

Danger

Hazard Statements

H332,H372,H411

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - STOT RE 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ2923
BCCG1180
BCCD8438
BCCD1905
BCCB8145

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T K Semennikova et al.
Gigiena truda i professional'nye zabolevaniia, (3)(3), 6-8 (1992-01-01)
Over 1000 workers of hydrofluoric and cryolite enterprises and electrolysis shops of aluminium enterprises were examined. Subjects exposed to soluble hydrofluorides presented in the early stage of chronic intoxication with a variety of syndromes, that was characteristic of intoxication with
S V Kuz'min et al.
Meditsina truda i promyshlennaia ekologiia, (6)(6), 14-17 (2012-09-25)
Federal budgetary establishment of a science "the Ekaterinburg medical centre of science of preventive maintenance and health protection of workers industrial plants". Findings are that adaptation level and life quality parameters progressively decrease with longer length of service. The most
Extended follow-up of cancer incidence in fluoride-exposed workers.
Philippe Grandjean et al.
Journal of the National Cancer Institute, 96(10), 802-803 (2004-05-20)
Liangshi Wang et al.
Journal of hazardous materials, 209-210, 77-83 (2012-01-28)
This paper investigates the development of a new environment friendly approach for treatment of bastnasite. A new process was developed to recover fluorine from bastnasite as synthetic cryolite by-product. The conditions affecting the fluorine removal and recovery in the process
Imidazolium ionic liquids in mineral processing.
Luczak J, et al.
Physicochemical Problems of Mineral Processing , 42, 223-236 (2008)
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