Annals of the New York Academy of Sciences, 1125, 215-229 (2007-12-22)
The history and changing function of tungsten as the heaviest element in biological systems is given. It starts from an inhibitory element/anion, especially for the iron molybdenum-cofactor (FeMoCo)-containing enzyme nitrogenase involved in dinitrogen fixation, as well as for the many
The toxicity of nanomaterials has been well known, but mechanisms involved have been little known. This study was aimed at looking at direct interaction between nanomaterials and naked DNA for some fundamental understanding. Two different types of nanomaterials, carbon nanotubes
Frontiers in bioscience : a journal and virtual library, 8, s813-s825 (2003-09-06)
Polyoxometalates (POM) have a rich and promising photochemical behavior. Upon illumination at the O M CT band (i.e., in UV and near-visible area) become powerful oxidizing reagents able to oxidize various organic compounds. In the process POM undergo stepwise reduction
Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases.
Angewandte Chemie (International ed. in English), 42(38), 4592-4633 (2003-10-09)
Catalytic olefin metathesis has quickly emerged as one of the most often-used transformations in modern chemical synthesis. One class of catalysts that has led the way to this significant development are the high-oxidation-state alkylidene complexes of molybdenum. In this review
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