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749192

Sigma-Aldrich

Poly(styrene-block-methyl methacrylate)

average Mn 104,000, block ratio of 1:1

Synonym(s):

PS-block-PMMA, PS-PMMA

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About This Item

CAS Number:
UNSPSC Code:
12162002

form

solid

mol wt

average Mn 104,000
average Mn 52,000 (PMMA)
average Mn 52,000 (polystyrene)

transition temp

Tm 345-350 °C

Mw/Mn

<1.2

InChI

1S/C8H8.C5H8O2/c1-2-8-6-4-3-5-7-8;1-4(2)5(6)7-3/h2-7H,1H2;1H2,2-3H3

InChI key

ADFPJHOAARPYLP-UHFFFAOYSA-N

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General description

57 kDa PS; 25 kDa PMMA; m ~494; n ~520
PS Mn = 57 ± 6 kg/mol
PMMA Mn = 25 ± 3 kg/mol
PDI of the overall block copolymer <1.2
PS molecular weight verified by SEC (taking an aliquot from the reaction mixture) and the PMMA molecular weight by NMR spectroscopy. The overall block copolymer molecular weight distribution would be determined by SEC.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Novel fabrication of 2D and 3D inverted opals and their application.
Jae Ah Lee et al.
Small (Weinheim an der Bergstrasse, Germany), 7(18), 2581-2586 (2011-08-03)
F N K Kwong et al.
The Journal of bone and joint surgery. British volume, 88(1), 120-122 (2005-12-21)
The outcome of a cemented hip arthroplasty is partly dependent on the type of cement which is used. The production of an interface gap between the stem and the cement mantle as a result of shrinkage of the cement, may
S J Breusch et al.
Acta orthopaedica Scandinavica, 72(1), 29-35 (2001-05-01)
In a cadaver study, we prepared 29 paired human cadaver femora using 3 different broaches of identical geometry but different surface characteristics. In one group of 20 pairs, preparation with chipped-toothed broaches was compared to diamond-shaped broaches; in the other
T Kinoshita
Shika zairyo, kikai = Journal of the Japanese Society for Dental Materials and Devices, 9(1), 86-101 (1990-01-01)
Methyl methacrylate (MMA)-p-styrene sulfonic acid copolymer (MS) was prepared and its adhesion to ground tooth substrates was evaluated. MS is crosslinked with Ca2+ supplied by hydroxyapatite in the smeared layer on the ground enamel and dentin, and sticks to their
A D Puckett et al.
Critical reviews in biomedical engineering, 28(3 - 4), 457-461 (2000-12-07)
Poly(methylmethacrylate) (PMMA) bone cements have been used for the fixation of hip and knee implants since the early 1960s. Aseptic loosening, related to fracture of the PMMA, continues to be the primary mode of failure for these prostheses. Failed prostheses

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