Skip to Content
Merck
All Photos(1)

Documents

327611

Sigma-Aldrich

Pentacarbonylchlororhenium(I)

98%

Synonym(s):

Rhenium(I) pentacarbonyl chloride

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
Re(CO)5Cl
CAS Number:
14099-01-5
Molecular Weight:
361.71
EC Number:
237-948-1
MDL number:
MFCD00013296
UNSPSC Code:
12161600
PubChem Substance ID:
24859674
NACRES:
NA.22

Assay

98%

reaction suitability

core: rhenium
reagent type: catalyst

SMILES string

Cl[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.ClH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1

InChI key

JQUUAHKBIXPQAP-UHFFFAOYSA-M

Application

Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. Employed in preparation of a series of mixed-valence compounds of rhenium and iron these compounds find application in the study of charge-transfer processes.

Other Notes

For a review of organometallic complexes of rhenium, see Science of Synthesis.

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Sci. Synth., 2, 111-111 (2003)
Pfennig, B.W. et al.
Inorganic Chemistry, 10, 606-606 (1999)
Stanislav R Stoyanov et al.
ACS omega, 5(22), 12944-12954 (2020-06-18)
The Re(I) dimer complex, [fac(CO)3(phen)Re1-N(py)COORe2(phen)fac(CO)3]+ (py = pyridine; phen = 1,10-phenanthroline), contains two different Re(I) centers 9.3 Å apart, one with a nitrogen donor and the other with an acetate donor from the bridging isonicotinate ligand. The complexes were characterized
Inorganic Chemistry, 29, 2909-2909 (1990)
Inorganic Chemistry, 29, 253-253 (1990)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service