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About This Item
Linear Formula:
Cl2C(OCH3)CO2CH3
CAS Number:
Molecular Weight:
172.99
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
97%
refractive index
n20/D 1.45 (lit.)
bp
179-181 °C (lit.)
density
1.36 g/mL at 25 °C (lit.)
SMILES string
COC(=O)C(Cl)(Cl)OC
InChI
1S/C4H6Cl2O3/c1-8-3(7)4(5,6)9-2/h1-2H3
InChI key
FWIGIASHGJFYOL-UHFFFAOYSA-N
Application
Methyl 2,2-dichloro-2-methoxyacetate was used in the preparation of methyl (Z)-α-methoxyacrylates via stereospecific two-carbon homologation of aldehydes under Barbier conditions.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
195.8 °F - closed cup
Flash Point(C)
91 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Stereoselective synthesis of methyl (Z)-a-methoxyacrylates via two-carbon homologation of aldehydes.
Baati R, et al.
Tetrahedron Letters, 50(4), 402-405 (2009)
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