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Sigma-Aldrich

Lithium L-aziridine-2-carboxylate

≥97.0% (dried material, NT)

Synonym(s):

L-Aziridine-2-carboxylic acid lithium salt

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About This Item

Empirical Formula (Hill Notation):
C3H4LiNO2
CAS Number:
Molecular Weight:
93.01
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:

Assay

≥97.0% (dried material, NT)

optical activity

[α]20/D −42±2°, c = 1% in H2O

impurities

~3% water

application(s)

peptide synthesis

SMILES string

[Li+].[O-]C(=O)[C@@H]1CN1

InChI

1S/C3H5NO2.Li/c5-3(6)2-1-4-2;/h2,4H,1H2,(H,5,6);/q;+1/p-1/t2-;/m0./s1

InChI key

ZGQWDLXRNCMIHH-DKWTVANSSA-M

Application

Lithium L-aziridine-2-carboxylate may be used as a chelate ligand to form complexes with transition metal salts.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Chiral building block; protected derivatives are used for the synthesis of various amino acids by ring-opening with nucleophiles

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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K. Nakajima et al.
Bulletin of the Chemical Society of Japan, 56, 520-520 (1983)
R.J. Parry et al.
Journal of the American Chemical Society, 107, 2512-2512 (1985)
Transition metal complexes of l-aziridine-carboxylate.
Hauck T, et al.
Inorgorganica Chimica Acta, 235(1-2), 391-396 (1995)
Y. Kogami et al.
Bulletin of the Chemical Society of Japan, 60, 2963-2963 (1987)

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