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400386

Sigma-Aldrich

Alane N,N-dimethylethylamine complex solution

0.5 M in toluene

Synonym(s):

(Ethyldimethylamine)trihydroaluminum, Dimethylethylamine alane

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About This Item

Linear Formula:
C2H5N(CH3)2 · AlH3
CAS Number:
124330-23-0
Molecular Weight:
103.14
MDL number:
MFCD00191709
UNSPSC Code:
12352116
PubChem Substance ID:
24864913
NACRES:
NA.22

form

liquid

Quality Level

100

reaction suitability

reagent type: reductant

concentration

0.5 M in toluene

density

0.837 g/mL at 25 °C

SMILES string

[AlH3].CCN(C)C

InChI

1S/C4H11N.Al.3H/c1-4-5(2)3;;;;/h4H2,1-3H3;;;;

InChI key

CXNFERZVFRNSPE-UHFFFAOYSA-N

Related Categories

Application

Alane N,N-dimethylethylamine complex solution can be used as a selective reducing agent for the reduction of brominated γ-lactams to synthesize dihydroflustramine C and flustramine E alkaloids.
Reactant for:
  • Preparation of aluminum nanoparticles
  • Fluorination reactions
  • Aluminum metal-organic chemical vapor deposition for the growth of aluminum films
  • Ligand-exchange reactions
  • Hydroalumination of nitriles and isonitriles

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2

Target Organs

Central nervous system

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

-4.0 °F

Flash Point(C)

-20 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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First total syntheses of dihydroflustramine C and flustramine E, alkaloids from the marine bryozoan Flustra foliacea.
Morales-Rios MS, et al.
Tetrahedron, 58(8), 1479-1484 (2002)
Hossein Robatjazi et al.
Science advances, 5(2), eaav5340-eaav5340 (2019-02-21)
Metal-organic frameworks (MOFs) and metal nanoparticles are two classes of materials that have received considerable recent attention, each for controlling chemical reactivities, albeit in very different ways. Here, we report the growth of MOF shell layers surrounding aluminum nanocrystals (Al

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