203548

Lanthanum(III) nitrate hexahydrate

99.999% trace metals basis

• Synonym(s): Nitric acid, lanthanum (III) salt, hexahydrate
• Linear Formula: La(NO₃)₃ · 6H₂O
• CAS Number: 10277-43-7
• Molecular Weight: 433.01
• EC Number: 233-238-0
• MDL number: MFCD00149751
• UNSPSC Code: 12352302
• PubChem Substance ID: 24852179
• NACRES: NA.23

Properties

• Assay: 99.999% trace metals basis
• form: solid
• reaction suitability: reagent type: catalyst; core: lanthanum
• impurities: ≤15.0 ppm Trace Rare Earth Analysis
• mp: 65-68 °C
• SMILES string: [La+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
• InChI: 1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;
• InChI key: GJKFIJKSBFYMQK-UHFFFAOYSA-N

Description

General description

Lanthanum(III) nitrate hexahydrate is a transition metal catalyst widely used in many organic transformations such as chemoselective deprotection of acetonides, acetylation of alcohols, phenols, and amines with acetic anhydride, and synthesis of α-amino nitriles. It can also be used as a precursor in the preparation of lanthanum-based nanoparticles.

Application

Lanthanum(III) nitrate hexahydrate can be used as a catalyst in the synthesis of:

• α-aminonitriles by a one-pot three-component coupling of the carbonyl compound, amine, and TMSCN.
• Acetals and geminal diacetates (acylals)from aldehydes.
• Bis(indolyl) methanes under solvent‐free conditions.

It can also be used as a starting material for the electrochemical synthesis of LaMnO₃ thin films and solvothermal synthesis of doped lanthanide oxysulfide (La₂O₂S).

Features and Benefits

• Thermal stability
• Low toxicity
• Mild reaction condition
• Chemoselectivity
• Low cost

Safety Information

• Pictograms: GHS03,GHS05,GHS09
• Signal Word: Danger
• Hazard Statements: H272,H318,H410
• Precautionary Statements: P210 - P220 - P273 - P280 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 2
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves