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Key Documents

MX0488

Supelco

Methanol

≥99.9% (GC), suitable for HPLC, OmniSolv®

Synonym(s):

Methyl alcohol

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About This Item

Linear Formula:
CH3OH
CAS Number:
Molecular Weight:
32.04
Beilstein:
1098229
MDL number:
UNSPSC Code:
41116121
EC Index Number:
200-659-6

product name

Methanol, gradient grade OmniSolv®, ≥99.9% (GC)

vapor density

1.11 (vs air)

Quality Level

100
300

vapor pressure

128 hPa ( 20 °C)
410 mmHg ( 50 °C)
97.68 mmHg ( 20 °C)

product line

OmniSolv®

Assay

≥99.9% (GC)

form

liquid

autoignition temp.

725 °F

expl. lim.

36 %

technique(s)

HPLC: suitable

impurities

≤0.05% Water (H2O)
≤0.2 μeq/g Titrable base
≤0.3 μeq/g Titrable acid
≤10 ppm Acetone

evapn. residue

≤1 ppm

color

APHA: ≤10

refractive index

n20/D 1.329 (lit.)

bp

64.7 °C (lit.)

mp

−98 °C (lit.)

transition temp

flash point 9.7 °C

density

0.791 g/mL at 25 °C (lit.)

UV cutoff

≤203 nm

UV absorption

λ: 203 nm Amax: ≤1.00
λ: 205 nm Amax: ≤0.80
λ: 210 nm Amax: ≤0.25
λ: 220 nm Amax: ≤0.10
λ: 230 nm Amax: ≤0.03
λ: 250 nm Amax: ≤0.01
λ: 260 nm Amax: ≤0.005
λ: 300 nm Amax: ≤0.005

format

neat

shipped in

ambient

storage temp.

room temp

SMILES string

CO

InChI

1S/CH4O/c1-2/h2H,1H3

InChI key

OKKJLVBELUTLKV-UHFFFAOYSA-N

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General description

Methanol, also known as Methyl alcohol, is a colorless organic solvent commonly used to dissolve substances with high and medium polarity. It is also used as a starting material/solvent for synthesis.

Application

Methanol is used as a solvent:
  • In the mobile phase during the reversed phase for high-performance liquid chromatography (HPLC) analysis.
  • To prepare the stock solution of Fluorescein dye.

Preparation Note

Product filtered through a 0.2 μm filter

Analysis Note

Acetone10ppm maxAssay (GC)99.9% minColor (APHA)10 maxEvaporation residue1ppm maxFiltered through 0.2 µm filterTo pass testFluorescence (as quinine base)250ppt maxFormClear liquidGradient at 235 nm0.001AU maxGradient at 254 nm0.001AU maxIdentity (IR-spectrum)ConformsRefractive index (at 20°C)1.327-1.329Titrable acid0.3µeq/g maxTitrable base0.2µeq/g maxUV Abs. at 203 nm1.00AU maxUV Abs. at 205 nm0.80AU maxUV Abs. at 210 nm0.25AU maxUV Abs. at 220 nm0.10AU maxUV Abs. at 230 nm0.03AU maxUV Abs. at 250 nm0.01AU maxUV Abs. at 260 nm0.005AU maxUV Abs. at 300 nm0.005AU maxUV Cut-off203nm maxWater (H2O)0.05% max
Evaporation Number: 1.9

Legal Information

OMNISOLV is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Target Organs

Eyes,Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

49.5 °F - closed cup

Flash Point(C)

9.7 °C - closed cup


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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High-performance liquid chromatographic stationary phases based on polysiloxanes with different chain lengths thermally immobilized on silica supports.
Edivan T, et al.
Journal of Chromatography A, 1119, 135-139 (2006)
Method validation for the determination of furosemide in plasma by liquid-liquid extraction and high-performance liquid chromatography with fluorescence detection.
CAROLINA GG, et al.
Journal of the Chilean Chemical Society, 50, 479-482 (2005)
Methanol
Gronemann O, et al.
Ullmann's Encyclopedia of Industrial Chemistry (2000)

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