Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

717398

Sigma-Aldrich

(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline

97%

Synonym(s):

(Sp)-1-(Diphenylphosphino)-2-[(4S)-4-isopropyl-2-oxazolyl]ferrocene

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C28H28FeNOP
CAS Number:
163169-29-7
Molecular Weight:
481.35
MDL number:
MFCD15144869
UNSPSC Code:
12352005
PubChem Substance ID:
329763485
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

optical activity

[α]20/D 366°, c = 0.1 in chloroform

mp

158-162 °C

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CC(C)[C@H]2COC(=N2)[C]3[CH][CH][CH][C]3P(c4ccccc4)c5ccccc5

InChI

1S/C23H23NOP.C5H5.Fe/c1-17(2)21-16-25-23(24-21)20-14-9-15-22(20)26(18-10-5-3-6-11-18)19-12-7-4-8-13-19;1-2-4-5-3-1;/h3-15,17,21H,16H2,1-2H3;1-5H;/t21-;;/m1../s1

InChI key

FELCHLOAEMNOQM-GHVWMZMZSA-N

Related Categories

Application

(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline can be used as a chiral ligand in the synthesis of rhodium, iridium, ruthenium, and osmium metal complexes.

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(Sp)-2-(diphenylphosphino) ferrocenyl]-4-isopropyloxazoline
Carmona D, et al.
Journal of Organometallic Chemistry, 691(26), 5560-5566 (2006)
Octahedral ruthenium (II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino) ferrocenyl]-4-(isopropyl) oxazoline (FcPN). X-Ray crystal structures of fac-[RuCl2 (PMe3) 2 (FcPN)] and fac-[RuCl2 (dppm)(FcPN)](dppm= bis (diphenylphosphino)methane)
Gimeno J, et al.
Journal of Organometallic Chemistry, 637, 463-468 (2001)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service