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690309

Sigma-Aldrich

Sodium dicyanamide

Arxada quality, ≥97.0 % (w/w) (T)

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About This Item

Linear Formula:
NaN(CN)2
CAS Number:
Molecular Weight:
89.03
Beilstein:
3913818
EC Number:
MDL number:
UNSPSC Code:
12352111
PubChem Substance ID:
NACRES:
NA.22

form

powder

quality

Arxada quality

manufacturer/tradename

Arxada AG

concentration

≥97.0 % (w/w) (T)

impurities

≤0.5 % (w/w) water (Karl Fischer)
≤3.0 % (w/w) NaCl (AT)

SMILES string

[Na]N(C#N)C#N

InChI

1S/C2N3.Na/c3-1-5-2-4;/q-1;+1

InChI key

IXBPPZBJIFNGJJ-UHFFFAOYSA-N

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Application

Reactant for preparation of:
  • Nickel diacetylpyridine dioximate pentanuclear, octanuclear and decanuclear cluster complexes
  • Decanuclear manganese(II/III) oxo azide diolate clusters as supertetrahedral building-blocks to design extended magnetic networks
  • Ruthenium bipyridine complexes entrapped in iron and manganese dicyanamide two-dimensional anionic sheet-like coordination polymeric networks exhibiting dual emission photoluminescence
  • Lead dicyanamide-bridged nitronyl nitroxide radical polymeric complex
  • Antiferromagnetically coupled hexanuclear copper(II) Schiff base complexes with dicyanamido bridges
  • CuII2L based polymeric ladders using dicyanamide bridges
  • Luminous hexacoordinated coordination polymers of cadmium(II), containing dicyanamide bridges

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Daniel Rauber et al.
Physical chemistry chemical physics : PCCP, 19(40), 27251-27258 (2017-10-11)
Ionic liquids (ILs) exhibit tunable behaviour and properties that are due to their supramolecular structure. We synthesized a series of alkylated and fluorinated phosphonium dicyanamide ILs to study the relation between molecular structure and assembly with a focus on the

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