Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
334995
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Synonym(s):
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
About This Item
Recommended Products
Quality Level
reaction suitability
core: ruthenium
reagent type: catalyst
mp
204-206 °C (dec.) (lit.)
SMILES string
Cl[Ru].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.CO.ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;1H;/q;;;;;+1/p-1
InChI key
MVJRXTSUBHUUPN-UHFFFAOYSA-M
General description
Application
- Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II): This ruthenium complex is used as a versatile catalyst for various reactions including hydrogenation, transfer hydrogenation, C-C bond-forming reactions, α-alkylation of ketones with primary alcohols, and as a precursor for pincer ruthenium carbonyl catalysts for hydrogenation. The complex is noted for its physical properties, such as decomposing above its melting point (204-206°C), and its solubility characteristics. It is very insoluble in water, ethanol, and DMSO, sparingly soluble in benzene and acetone, and slightly soluble in chloroform (Kuriyama, 2001).
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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