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104817

Sigma-Aldrich

Trichloro(octadecyl)silane

≥90%

Synonym(s):

Octadecyltrichlorosilane

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About This Item

Linear Formula:
CH3(CH2)17SiCl3
CAS Number:
112-04-9
Molecular Weight:
387.93
Beilstein:
1778847
EC Number:
203-930-7
MDL number:
MFCD00000484
UNSPSC Code:
12352103
PubChem Substance ID:
24846677
NACRES:
NA.23

vapor density

>1 (vs air)

vapor pressure

<5 mmHg ( 20 °C)

Assay

≥90%

refractive index

n20/D 1.459 (lit.)

bp

223 °C/10 mmHg (lit.)

density

0.984 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCCCCCCCCC[Si](Cl)(Cl)Cl

InChI

1S/C18H37Cl3Si/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-22(19,20)21/h2-18H2,1H3

InChI key

PYJJCSYBSYXGQQ-UHFFFAOYSA-N

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General description

Self-assembled monolayers (SAMs) are used as passivating layers and for controlled modification of surface properties of substrates. Their main applications include wetting, adhesion, friction, chemical sensing and ultra-fine scale lithography. Alkytrichlorosilanes are commonly used for synthesising SAMs on Silicon dioxide which are commonly used in microelectronics. Trichloro(octadecyl)silane is a widely used alkyltrichlorosilane.
Trichloro(octadecyl)silane (OTS) is an alkoxy silane with a large alkyl and polar head group, mainly used as a self-assembled monolayer (SAM) on a variety of nanoparticles and metal oxides substrates. It provides an amphiphilic character that can be used in molecular and opto-electronics applications.

Application

OTS can be used to silanize poly(vinylalcohol) (PVA)/nanosilica (SiO2) nanofibers that can provide a hydrophobic coating on the wooden surfaces by electrospinning. It can also be used as a SAM on the surface of silica (SiO2) gate dielectric for the development of organic field effect transistor (OFETs). It may also be used in a variety of applications like improving the electrochemical performance for dye sensitized solar cells and for the development of metal insulated field effect transistors.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

404.6 °F - closed cup

Flash Point(C)

207 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Structural evaluation of 5, 5'-bis (naphth-2-yl)-2, 2'-bithiophene in organic field-effect transistors with n-octadecyltrichlorosilane coated SiO2 gate dielectric.
Ejdrup A, et al.
Langmuir, 34 (23), 6727?6736-6727?6736 (2018)
Surface Characteristics of Silicon Nanowires/Nanowalls Subjected to Octadecyltrichlorosilane Deposition and n-octadecane Coating.
Yilbas BS, et al.
Scientific reports, 6, 38678-38678 (2016)
Fabrication and Characterization of Flexible Metal-Insulator-Semiconductor Field Effect Transistor (MISFET) using Organic ODS and Inorganic ZrO2 as Dielectric Stack Materials.
Haridas PP, et al.
International Journal of Trend in Research and Development, 4, 2394-2394 (2017)
Coating of wood by means of electrospun nanofibers based on PVA/SiO2 and its hydrophobization with octadecyltrichlorosilane (OTS).
Kumar A, et al.
Holzforschung, 71(3), 225-231 (2017)
Shao-Yu Chen et al.
Nano letters, 12(2), 964-969 (2012-01-10)
In this article, we present the transport and magnetotransport of high-quality graphene transistors on conventional SiO(2)/Si substrates by modification with organic molecule octadecyltrichlorosilane (OTS) self-assembled monolayers (SAMs). Graphene devices on OTS SAM-functionalized substrates with high carrier mobility, low intrinsic doping
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