727695
1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
≥98.5% (HPLC)
Synonym(s):
AMIMTFSI
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About This Item
Empirical Formula (Hill Notation):
C9H11F6N3O4S2
CAS Number:
Molecular Weight:
403.32
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
≥98.5% (HPLC)
form
liquid
impurities
≤1% water
functional group
fluoro
SMILES string
C[n+]1ccn(CC=C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
InChI
1S/C7H11N2.C2F6NO4S2/c1-3-4-9-6-5-8(2)7-9;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3,5-7H,1,4H2,2H3;/q+1;-1
InChI key
DHMWATGUEVQTIY-UHFFFAOYSA-N
1 of 4
This Item | 727709 | 43961 | 77896 |
|---|---|---|---|
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| form liquid | form liquid | form crystals | form liquid |
| impurities ≤1% water | impurities ≤1.0% water | impurities - | impurities ≤0.5% water |
| functional group fluoro | functional group amine | functional group - | functional group fluoro |
General description
1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide is an ionic liquid that can be prepared by reacting 1-allyl-3-methylimidazolium chloride and lithium bis(trifluoromethylsulfonyl)imide under microwave conditions.[1]
Application
1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide can be used to prepare AMIMTFSI-propylene carbonate based electrolyte, with potential application in lithium-ion batteries.[1] It also finds application in alkanes/alkenes separation process.[2] AMIMTFSI can be used as a surface protector to develop luminescent silicon nanoparticles.[3]
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Liquid?liquid equilibrium data for {heptane+ aromatic+ 1-(2-hydroxyethyl)-3-methylimidazolium bis (trifluoromethylsulfonyl) imide ([hemim][NTf2])} ternary systems
Ebrahimi, M., et al.
Journal of Chemical and Engineering Data, 59.2, 197-204 (2014)
Luminescent silicon nanoparticles covered with ionic liquid.
Miyano M, et al.
Materials Letters, 141, 359-361 (2015)
Synthesis and properties of pyrrolidinium and piperidinium bis (trifluoromethanesulfonyl) imide ionic liquids with allyl substituents
Yim, Tae Eun, et al.
J. Korean Chem. Soc., 28.9, 1567-1567 (2007)
Mixtures of unsaturated imidazolium based ionic liquid and organic carbonate as electrolyte for Li-ion batteries.
Wang M, et al.
Electrochimica Acta, 95, 301-307 (2013)
(Liquid+ liquid) equilibrium for the ternary systems {heptane+ toluene+ 1-allyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide} and {heptane+ toluene+ 1-methyl-3-propylimidazolium bis (trifluoromethylsulfonyl) imide} ionic liquids
Garcia, Silvia, et al.
The Journal of Chemical Thermodynamics, 43.11, 1641-1645 (2011)
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