678015
4,7-Dichloro-1,10-phenanthroline
97%
Synonym(s):
4,7-Dichloro-o-phenanthroline
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About This Item
Empirical Formula (Hill Notation):
C12H6Cl2N2
CAS Number:
Molecular Weight:
249.10
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
form
solid
mp
243-247 °C
SMILES string
Clc1ccnc2c1ccc3c(Cl)ccnc23
InChI
1S/C12H6Cl2N2/c13-9-3-5-15-11-7(9)1-2-8-10(14)4-6-16-12(8)11/h1-6H
InChI key
GIEQBYJCGYHHSU-UHFFFAOYSA-N
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Anna M Maroń et al.
Dalton transactions (Cambridge, England : 2003), 49(14), 4441-4453 (2020-03-18)
Three Re(i) carbonyl complexes [ReCl(CO)3(Ln)] bearing 2,2'-bipyridine, 2,2':6',2''-terpyridine, and 1,10-phenanthroline functionalized with diphenylamine/or triphenylamine units (L1-L3) were synthesized to explore the impact of highly electron donating units appended to the imine ligand on the thermal and optoelectronic properties of Re(i)
Ryan A Altman et al.
Organic letters, 8(13), 2779-2782 (2006-06-16)
[reaction: see text] 4,7-Dimethoxy-1,10-phenanthroline (L) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazole with aryl iodides and bromides under mild conditions. A variety of hindered and functionalized imidazoles and aryl halides were transformed in good
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