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Merck

34850

Sigma-Aldrich

Acetona

suitable for HPLC, ≥99.8%

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About This Item

Fórmula lineal:
CH3COCH3
Número de CAS:
Peso molecular:
58.08
Beilstein/REAXYS Number:
635680
EC Number:
MDL number:
UNSPSC Code:
41116105
eCl@ss:
39021201
PubChem Substance ID:

vapor density

2 (vs air)

Quality Level

vapor pressure

184 mmHg ( 20 °C)

assay

≥99.8%

form

liquid

expl. lim.

13.2 %

technique(s)

HPLC: suitable

impurities

≤0.0005% non-volatile matter
≤0.002% free acid (as CH3COOH)
≤0.1% water (Karl Fischer)

transmittance

330 nm, ≥15%
335 nm, ≥50%
340 nm, ≥80%
350 nm, ≥98%

refractive index

n20/D 1.359 (lit.)

pH

5-6 (20 °C, 395 g/L)

bp

56 °C/760 mmHg (lit.)

mp

−94 °C (lit.)

density

0.791 g/mL at 25 °C (lit.)

format

neat

SMILES string

CC(C)=O

InChI

1S/C3H6O/c1-3(2)4/h1-2H3

InChI key

CSCPPACGZOOCGX-UHFFFAOYSA-N

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General description

Mixtures of TiO2 (P25) with rare earth oxides (La2O3 or Y2O3) calcined at 700°C or 650°C efficiently causes oxidation of acetone. Its Aldol condensation in vapor-phase has been investigated over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions. It undergoes Aldol condensation in the presence of Mg-Al layered double hydroxides (LDH) as catalysts and Cl- and/or CO32- as compensating anions to afford diacetone alcohol and mesityl oxide. Enantioselective Aldol condensation of acetone with various isatins in the presence of dipeptides (catalyst) has been described.

Application

La intensidad de luminiscencia de la acetona depende de los componentes de la disolución . La absorción de luz ultravioleta por la acetona tiene como consecuencia su fotólisis y la producción de radiales .
Acetone has been used in the preparation of 13wt% amorphous poly (lactic acid) (PLA) solution, which was required for the preparation of electrospun PLA membranes.

Other Notes

Important notice
  • The article number 34850-4X2.5L will be discontinued. Please order the single bottle 34850-2.5L which is physically identical with the same exact specifications.
  • The article number 34850-6X1L will be discontinued. Please order the single bottle 34850-1L which is physically identical with the same exact specifications.

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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

1.4 °F - closed cup

flash_point_c

-17.0 °C - closed cup


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Los clientes también vieron

Slide 1 of 6

1 of 6

Development of eco-efficient micro-porous membranes via electrospinning and annealing of poly (lactic acid).
Li L, et al.
Journal of Membrane Science, 436, 57-67 (2013)
An investigation on photocatalytic activities of mixed TiO2-rare earth oxides for the oxidation of acetone in air.
Lin J and Jimmy CY.
Journal of Photochemistry and Photobiology A: Chemistry, 116(1), 63-67 (1998)
Aldol condensation of acetone over layered double hydroxides of the meixnerite type.
Tichit D, et al.
Applied Clay Science, 13(5), 401-415 (1998)
Base catalysis for the synthesis of α,β-unsaturated ketones from the vapor-phase aldol condensation of acetone.
Di Cosimo JI, et al.
Applied Catalysis A: General, 137(1), 149-166 (1996)
Gianluigi Luppi et al.
The Journal of organic chemistry, 70(18), 7418-7421 (2005-08-27)
[reaction: see text] The aldol condensation of acetone with several isatins is described. The desired compound was obtained in quantitative yield and with good enantioselectivities up to 77%. The best results were obtained with 10 mol % H-D-Pro-L-beta3-hPhg-OBn as a

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