222283

Magnesium perchlorate

ACS reagent

• Fórmula lineal: Mg(ClO₄)₂
• Número de CAS: 10034-81-8
• Peso molecular: 223.21
• EC Number: 233-108-3
• MDL number: MFCD00011102
• UNSPSC Code: 12352300
• PubChem Substance ID: 329752290
• NACRES: NB.24

Propiedades

• grade: ACS reagent
• Quality Level: 200
• form: flakes; powder, chunks or granules
• reaction suitability: reagent type: oxidant
• concentration: >10% Mg (EDTA titration)
• impurities: ≤0.005 meq/g Titr. free acid; ≤0.025 meq/g Titr. base
• loss: ≤8% loss on drying
• suitability: passes test for moisture absorption
• SMILES string: [Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• InChI: 1S/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2
• InChI key: MPCRDALPQLDDFX-UHFFFAOYSA-L

Descripción

General description

Magnesium perchlorate (Mg(ClO₄)₂) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l.

Application

Magnesium perchlorate (Mg(ClO₄)₂) may be employed as a catalyst in the following studies:

• Preparation of α-aminophosphonates.
• Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one.
• Preparation of imines and phenylhydrazones.
• Protection of alcohols in the form of t-butyl ethers.

Magnesium perchlorate may be used as a catalyst in the synthesis of the following compounds:

• α-Aminophosphonates via three-component reaction between an amine, an aldehyde or a ketone and a di-/trialkyl phosphite.
• Imines and phenylhydrazones by the condensation of carbonyl compounds with amines and phenylhydrazine.
• Knoevenagel adducts via Knoevenagel condensation between β-diketones and aliphatic or aromatic aldehydes.

It may also be used to catalyze the protection of alcohols as t-butyl ethers.

Información de seguridad

• pictograms: GHS03,GHS07
• signalword: Danger
• hcodes: H272,H315,H319,H335
• pcodes: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 5.1A - Strongly oxidizing hazardous materials
• wgk_germany: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable