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210013

Sigma-Aldrich

Hydriodic acid

contains no stabilizer, distilled, 57 wt. % in H2O, 99.99% trace metals basis

Sinónimos:

Hydriotic acid

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About This Item

Fórmula empírica (notación de Hill):
HI
Número de CAS:
10034-85-2
Peso molecular:
127.91
Número MDL:
MFCD00011347
Código UNSPSC:
12352106
ID de la sustancia en PubChem:
329752069
NACRES:
NA.21
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Nivel de calidad

100

Ensayo

99.99% trace metals basis

Formulario

liquid

no contiene

stabilizer

concentración

57 wt. % in H2O

bp

127 °C (lit.)

mp

-50 °C

densidad

1.701 g/mL at 25 °C

temp. de almacenamiento

room temp

cadena SMILES

I

InChI

1S/HI/h1H

Clave InChI

XMBWDFGMSWQBCA-UHFFFAOYSA-N

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Descripción general

Hydriodic acid (HI) along with red phosphorus (HI/red P) plays the role of a reducing agent for the preparation of methamphetamine.[1] HI/Phosphorous causes the reduction of various polycyclic quinones.[2] HI also participates as a reducing agent for the conversion of various polyarene quinones, hydroquinones and phenols to the corresponding aromatic hydrocarbons.[2]
Hydriodic acid is hydrogen iodide gas dissolved in water. It is a strong acid generally used as a reducing agent.[3]

Aplicación

Hydriodic acid may be used in the synthesis of trideuterio-[13C]-methyl iodide and [13C]-methyl iodide.[4]

Pictogramas

CorrosionEnvironment
GHS05,GHS09

Palabra de señalización

Danger

Frases de peligro

H290,H314,H411

Clasificaciones de peligro

Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Código de clase de almacenamiento

8B - Non-combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCX4587
MKCX4589
MKCX4586
MKCX3131
MKCX3132

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A practical laboratory route to the synthesis of trideuteriomethyl-[13C] iodide.
Coumbarides GS, et al.
Journal of Labelled Compounds & Radiopharmaceuticals, 46(4), 291-296 (2003)
Patnaik P.
A Comprehensive Guide to the Hazardous Properties of Chemical Substances, 123 (2007)
Efficient reduction of polycyclic quinones, hydroquinones, and phenols with hydriodic acid.
Konieczny M and Harvey RG.
The Journal of Organic Chemistry, 44(26), 4813-4816 (1979)
Kazumasa Wakamatsu et al.
Pigment cell & melanoma research, 22(4), 474-486 (2009-06-06)
Pheomelanogenesis is a complex pathway that starts with the oxidation of tyrosine (or DOPA, 3,4-dihydroxyphenylalanine) by tyrosinase in the presence of cysteine, which results in the production of 5-S-cysteinyldopa and its isomers. Beyond that step, relatively little has been clarified
Relationships between circulating and intracellular thyroid hormones: physiological and clinical implications.
P R Larsen et al.
Endocrine reviews, 2(1), 87-102 (1981-01-01)
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Questions

1–3 of 3 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. Is this genuine HI acid? If yes then will I get it in a glass bottle or what?

    1 answer

    1. This product is 57 wt. % Hydriodic acid in H2O that contains no stabilizer. This product will be packaged in an amber glass bottle.

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