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240486

2-Methyl-2-butanol

≥99%, liquid, suitable for synthesis, ReagentPlus®

Sinónimos:

tert-Amyl alcohol, tert-Pentyl alcohol

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Fórmula lineal:
CH3CH2C(CH3)2OH
Número CAS:
Peso molecular:
88.15
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
200-908-9
MDL number:
Beilstein/REAXYS Number:
1361351
Assay:
≥99%
Bp:
102 °C (lit.)
Vapor pressure:
12 mmHg ( 20 °C)
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Nombre del producto

2-Methyl-2-butanol, ReagentPlus®, ≥99%

vapor density

3 (vs air)

Quality Segment

vapor pressure

12 mmHg ( 20 °C)

product line

ReagentPlus®

assay

≥99%

form

liquid

autoignition temp.

819 °F

expl. lim.

9 %

dilution

(for general lab use)

refractive index

n20/D 1.405 (lit.)

bp

102 °C (lit.)

mp

−12 °C (lit.)

density

0.805 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

CCC(C)(C)O

InChI

1S/C5H12O/c1-4-5(2,3)6/h6H,4H2,1-3H3

InChI key

MSXVEPNJUHWQHW-UHFFFAOYSA-N

General description

2-Methyl-2-butanol is a sterically hindered alcohol.

Application

2-Methyl-2-butanol may be used as a solvent in the following processes:
  • Palladium (II)-catalyzed ortho-C–H olefination of phenylacetic acids.
  • Rhodium-catalyzed direct C-H functionalization at the C7 position of N-pivaloylindoles.

It may also be used in the preparation of 2-chloro-2-methylbutane by reacting with concentrated hydrochloric acid.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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72112315246319954
Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

assay

≥99%

assay

≥99%

assay

99%

assay

≥99.5% (GC)

form

liquid

form

liquid

form

liquid

form

-

autoignition temp.

819 °F

autoignition temp.

819 °F

autoignition temp.

819 °F

autoignition temp.

819 °F

density

0.805 g/mL at 25 °C (lit.)

density

0.805 g/mL at 25 °C (lit.)

density

0.805 g/mL at 25 °C (lit.)

density

0.805 g/mL at 25 °C (lit.)

refractive index

n20/D 1.405 (lit.)

refractive index

n20/D 1.405 (lit.)

refractive index

n20/D 1.405 (lit.)

refractive index

n20/D 1.405


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

Clase de almacenamiento

3 - Flammable liquids

wgk

WGK 1

flash_point_f

68.9 °F - closed cup

flash_point_c

20.5 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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