02482

Cyclohexanone

analytical standard

• Fórmula lineal: C₆H₁₀(=O)
• Número CAS: 108-94-1
• Peso molecular: 98.14
• UNSPSC Code: 41116107
• NACRES: NA.24
• PubChem Substance ID: 329747444
• EC Number: 203-631-1
• Beilstein/REAXYS Number: 385735
• MDL number: MFCD00001625

Propiedades

• grade: analytical standard
• Quality Segment: 100
• vapor density: 3.4 (vs air)
• vapor pressure: 3.4 mmHg ( 20 °C)
• assay: ≥99.9% (GC)
• autoignition temp.: 788 °F
• shelf life: limited shelf life, expiry date on the label
• expl. lim.: 1.1 %, 100 °F, 9.4 %
• technique(s): HPLC: suitable, gas chromatography (GC): suitable
• refractive index: n20/D 1.450 (lit.), n20/D 1.451
• bp: 155 °C (lit.)
• mp: −47 °C (lit.)
• density: 0.947 g/mL at 25 °C (lit.)
• application(s): cleaning products; cosmetics; environmental; flavors and fragrances; food and beverages; personal care
• format: neat
• SMILES string: O=C1CCCCC1
• InChI: 1S/C6H10O/c7-6-4-2-1-3-5-6/h1-5H2
• InChI key: JHIVVAPYMSGYDF-UHFFFAOYSA-N

Descripción

General description

Cyclohexanone is a cycloalkanone. It is an industrially important intermediate. It is useful for the preparation of raw materials for various chemical intermediates, such as caprolactam for nylon 6 and adipic acid for nylon 66 synthesis of nylon. It can be synthesized industrially by either the oxidation of cyclohexane or the hydrogenation of phenol.

Application

Cyclohexanone may be used for the following syntheses:

• vitamin A
• 2-cyclohexylidene cyclohexanone via Aldol condensation reaction
• 2-cyclohexenyl cyclohexanone via Aldol condensation reaction
• bis-(arylmethylidene)cycloalkanones by cross-aldol condensation with aldehydes

Información de seguridad

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H226,H302 + H312 + H332,H315,H318,H335
• pcodes: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Clase de almacenamiento: 3 - Flammable liquids
• wgk: WGK 1
• flash_point_f: 111.2 °F - closed cup
• flash_point_c: 44 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter