1.02442
Cloroformo
for analysis (for determinations with dithizone)
Sinónimos:
Triclorometano, Tricloruro de metilidino
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vapor density
4.1 (vs air)
Quality Segment
vapor pressure
160 mmHg ( 20 °C)
assay
99.0-99.4% (GC)
form
liquid
potency
695 mg/kg LD50, oral (Rat), >3980 mg/kg LD50, skin (Rabbit)
dilution
(for analytical testing)
impurities
≤0.0001% Chloride (Cl), ≤0.001% Free acid (as HCl), ≤0.005% Carbonyl compounds (as CO), ≤0.01% Carbon tetrachloride (GC), ≤0.01% Dichloromethane (GC), ≤0.01% Tetrachloroethylene (GC), ≤0.01% Trichloroethylene (GC), ≤0.01% Water, 0.6-1% Ethanol (GC), 0.6-1.0% Ethanol (GC)
evapn. residue
≤0.001%
refractive index
n20/D 1.445 (lit.)
bp
60.5-61.5 °C (lit.)
mp
−63 °C (lit.)
density
1.492 g/mL at 25 °C (lit.)
cation traces
Al: ≤0.00005%, B: ≤0.000002%, Ba: ≤0.00001%, Ca: ≤0.00005%, Cd: ≤0.000005%, Co: ≤0.000002%, Cr: ≤0.000002%, Cu: ≤0.000002%, Fe: ≤0.00001%, Mg: ≤0.00001%, Mn: ≤0.000002%, Ni: ≤0.000002%, Pb: ≤0.00001%, Sn: ≤0.00001%, Zn: ≤0.00001%
storage temp.
2-30°C
SMILES string
ClC(Cl)Cl
InChI
1S/CHCl3/c2-1(3)4/h1H
InChI key
HEDRZPFGACZZDS-UHFFFAOYSA-N
Application
- Characterization of Natural Products: Chloroform is extensively used in the extraction and isolation of natural products. A study on the characterization and pesticidal evaluation of diterpenes isolated from chloroform extracts of Hedychium spicatum rhizomes highlights its effectiveness. This application is crucial for identifying bioactive compounds and assessing their potential uses in pharmaceuticals and agrochemicals (Rawat et al., Analytical Chemistry Letters, 2023).
- Self-Diffusion and Molecular Association Studies: Chloroform is used in studies of self-diffusion and molecular association in binary systems, such as dimethyl sulfoxide (DMSO) and acetone. These studies provide insights into the molecular interactions and dynamics in mixed solvents, which are essential for understanding solvation and reaction mechanisms in various chemical processes (Gurina and Golubev, Results in Chemistry, 2022).
- Cell-Free DNA Isolation: A novel phenol-chloroform-free method for isolating cell-free DNA from cell-conditioned media has been developed, optimized, and compared with traditional methods. This advancement is significant for genomic studies, allowing for more efficient and less hazardous extraction of nucleic acids from biological samples (Das et al., Analytical Biochemistry, 2024).
- Green Chemistry and Circular Economy: Chloroform plays a role in green analytical chemistry, particularly in the development of circular chemistry principles. Research emphasizes the need to design chemical processes that minimize waste and environmental impact, promoting sustainability in analytical laboratories. This includes the use of chloroform in recyclable and reusable systems to reduce solvent waste (Psillakis and Pena-Pereira, TrAC Trends in Analytical Chemistry, 2024).
Other Notes
1 of 1
Este artículo | |||
|---|---|---|---|
| description for analysis (for determinations with dithizone) | description for analysis EMSURE® ACS,ISO,Reag. Ph Eur | description for gas chromatography ECD and FID SupraSolv® | description puriss. p.a., reag. ISO, reag. Ph. Eur., 99.0-99.4% (GC) |
| assay 99.0-99.4% (GC) | assay ≥99.8%, 90-99.4% (GC) | assay ≥99.8% (GC) | assay 99.0-99.4% (GC) |
| Quality Level 300 | Quality Level 300 | Quality Level 100 | Quality Level 200 |
| form liquid | form liquid | form liquid | form liquid |
| refractive index n20/D 1.445 (lit.) | refractive index n20/D 1.445 (lit.) | refractive index n20/D 1.445 (lit.) | refractive index n20/D 1.445 (lit.) |
| impurities ≤0.0001% Chloride (Cl), ≤0.005% Carbonyl compounds (as CO), ≤0.01% Dichloromethane (GC), ≤0.01% Trichloroethylene (GC), 0.6-1% Ethanol (GC), ≤0.001% Free acid (as HCl), ≤0.01% Tetrachloroethylene (GC), 0.6-1.0% Ethanol (GC), ≤0.01% Carbon tetrachloride (GC), ≤0.01% Water | impurities - | impurities - | impurities ≤0.00001% free chlorine (Cl), ≤0.00005% free acid (as HCl), ≤0.0005% non-volatile matter, ≤0.005% aldehydes and ketones (as CH3COCH3), ≤0.005% carbonyl compounds (as CO), ≤0.01% tetrachloroethene (GC), ≤0.01% tetrachloromethane (GC), ≤0.01% trichloroethene (GC), ≤0.01% water (Karl Fischer), ≤0.03% dichloromethane (GC), 0.6-1.0% ethanol (GC) |
| cation traces Al: ≤0.00005%, Ba: ≤0.00001%, Cd: ≤0.000005%, Cr: ≤0.000002%, Fe: ≤0.00001%, Mn: ≤0.000002%, Pb: ≤0.00001%, Zn: ≤0.00001%, B: ≤0.000002%, Co: ≤0.000002%, Mg: ≤0.00001%, Sn: ≤0.00001%, Ca: ≤0.00005%, Ni: ≤0.000002%, Cu: ≤0.000002% | cation traces - | cation traces - | cation traces Al: ≤0.5 mg/kg, B: ≤0.02 mg/kg, Ba: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Ni: ≤0.02 mg/kg, Pb: ≤0.05 mg/kg, Sn: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg |
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3
wgk
WGK 3
flash_point_f
does not flash
flash_point_c
does not flash
target_organs
Central nervous system, Liver,Kidney
Clase de almacenamiento
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
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