1.01245

Isopentyl nitrite

extra pure stabilized with potassium carbonate

• Sinónimos: Isopentyl nitrite, iso-Amyl nitrite, iso-Pentyl nitrite, Nitrous acid isoamyl ester
• Fórmula empírica (notación de Hill): C₅H₁₁NO₂
• Número CAS: 110-46-3
• Peso molecular: 117.15
• UNSPSC Code: 12352108
• EC Index Number: 203-770-8
• NACRES: NA.22
• MDL number: MFCD00002057

Propiedades

• Quality Segment: 200
• form: liquid
• autoignition temp.: 208 °C
• potency: 505 mg/kg LD₅₀, oral (Rat)
• bp: 97-99 °C/1013 hPa
• transition temp: flash point -18 °C
• density: 0.872 g/cm³ at 20 °C
• storage temp.: 2-8°C
• SMILES string: N(=O)OCCC(C)C
• InChI: 1S/C5H11NO2/c1-5(2)3-4-8-6-7/h5H,3-4H2,1-2H3
• InChI key: OWFXIOWLTKNBAP-UHFFFAOYSA-N

Descripción

Application

• Deaminative coupling of benzylamines and arylboronic acids: Research demonstrated the use of isopentyl nitrite in the deaminative coupling of benzylamines and arylboronic acids, showcasing its application in creating complex molecules for pharmaceutical and chemical manufacturing processes (Sirvinskaite, Reisenbauer, and Morandi, 2023).
• Syntheses of Arylazo Phosphine Oxides and Phosphonates: Utilizing isopentyl nitrite, research facilitated the synthesis of arylazo phosphine oxides and phosphonates via N-P bond formation under blue LED light conditions, contributing to developments in organophosphorus chemistry (Shen et al., 2022).

Analysis Note

Total nitrites (GC): ≥ 97.0 % (a/a)
Identity (IR-spectrum): conforms
Free acid: conforms
Density (d 20 °C/ 4 °C): 0.8720 - 0.8770
Non volatile matter: ≤ 0.04 %

Información de seguridad

• Pictogramas: GHS02,GHS08,GHS05,GHS07
• Palabra de advertencia: Danger
• Códigos de peligro: H225,H302 + H332,H314,H317,H341
• Indicaciones de precaución: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1
• Clase de almacenamiento: 3 - Flammable liquids
• ¿Qué está pasando?: WGK 3
• Punto de inflamación (°F): -4.0 °F - closed cup
• Punto de inflamación (°C): -20 °C - closed cup