900349

cataCXium Pd G4

• Sinónimos: [di(adamantan-1-yl)(butyl)phosphine](methanesulfonato-κO)[2′-(methylamino)-2-biphenylyl]palladium
• Fórmula empírica (notación de Hill): C₃₈H₅₄NO₃PPdS
• Número de CAS: 2230788-67-5
• Peso molecular: 742.30
• UNSPSC Code: 12352103
• PubChem Substance ID: 329769810
• NACRES: NA.22

Propiedades

• form: powder
• Quality Level: 100
• feature: generation 4
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• functional group: phosphine
• SMILES string: CCCCP([C@@]12C[C@H]3C[C@@H](C1)C[C@@H](C2)C3)[C@@]4(C5)C[C@H]6C[C@H](C[C@@H]5C6)C4.CNC7=C(C8=CC=CC=C8[Pd]OS(C)(=O)=O)C=CC=C7
• InChI: 1S/C24H39P.C13H12N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h17-22H,2-16H2,1H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1
• InChI key: ROZFJYIWIVSDBR-UHFFFAOYSA-M

Descripción

Application

A fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3