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802557

Sigma-Aldrich

Aquivion® D98-25BS

greener alternative

liquid, dispersion, 25% in water, PFSA eq. wt. 980 g/mole SO3H, contains CF3 polymer chain ends as stabilizer

Sinónimos:

Aquivion® SO3H-form, Tetrafluoroethylene-perfluoro(3-oxa-4-pentenesulfonic acid) copolymer, Ethanesulfonic acid

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About This Item

Fórmula lineal:
(C4HF7O4S .C2F4)x
Código UNSPSC:
26111700
NACRES:
NA.23
En este momento no podemos mostrarle ni los precios ni la disponibilidad

Nivel de calidad

Formulario

dispersion
liquid

peso equivalente

980±40g/mole (SO3H)

contiene

CF3 polymer chain ends as stabilizer

composición

25% in water

características de los productos alternativos más sostenibles

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentración

25±1 % (w/w)

categoría alternativa más sostenible

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Descripción general

Aquivion® PFSA dispersions are derived from a short-side-chain (SSC) copolymer of Tetrafluoroethylene and Sulfonyl Fluoride Vinyl Ether (SFVE), CF2=CF2-O-(CF2)2-SO2F, industrially produced by Syensqo Group. The resulting perfluoropolymer features functional groups in their sulfonic acid form (SO3H). Aquivion® D98-25BS is a perfluorosulfonic acid (PFSA) ionomer dispersion with an Equivalent Weight (EW) of 980 g/eq. The EW of an ionomer represents the weight of the polymer required to provide 1 mole of exchangeable protons, inversely related to the ion exchange capacity (IEC). This dispersion is chemically stabilized, with a significant proportion of polymer end groups converted to an inert trifluoromethyl (CF3) configuration, enhancing the polymer′s lifetime. Aquivion® D98-25BS contains a polymer concentration of 25 wt% in a solvent system that is over 99% water and free of ethers.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency and is intended for use as Proton Exchange Membrane (PEM) Fuel Cells. Click here for more information.

Aplicación

The superacidity of Aquivion® PFSA resins, combined with their high functional group concentration and electrochemical stability, makes them a critical ingredient in heterogeneous catalysts. Due to their excellent proton conductivity at low water uptake, these resins are frequently employed in research as ionomer binders within the catalyst layers of proton exchange membranes (PEM) for fuel cells and water electrolyzers. Additionally, they can be used in fabricating separator membranes (PEMs) either as stand-alone materials or reinforced with PTFE and are sometimes added to the surfaces of specialty fluoropolymers to enhance wettability. Aquivion® D98-25BS, with its short side chain and high equivalent weight, is a promising ionomer for balancing catalyst activity and stability. Ionomers with higher equivalent weights, such as D98-25BS, exhibit greater durability in long-term electrochemical stability tests. Moreover, D98-25BS ionomer catalysts can form smaller aggregates and agglomerates in certain catalyst systems. In these instances, the enhanced interaction between the catalyst and the D98-25BS binder can improve reaction kinetics, reduce overpotential, and enhance catalyst utilization compared to lower equivalent weight ionomers.

Características y beneficios

  • Very high concentration of functional groups for strong proton (or Na+, K+, Li+, etc.) conductivity
  • High softening point for high temperature operation well above 80 ºC
  • Strong water retention for better fuel cell operation at low-humidity conditions for membranes or catalyst inks that are utilizing this dispersion material

Información legal

Aquivion is a registered trademark of Syensqo Group

Pictogramas

Corrosion

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Eye Dam. 1 - Skin Corr. 1C

Código de clase de almacenamiento

8A - Combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Artículos

Advances in electrochemical water conversion and understanding PEMFC degradation drive progress in hydrogen technologies.

Advances in electrochemical water conversion and understanding PEMFC degradation drive progress in hydrogen technologies.

Advances in electrochemical water conversion and understanding PEMFC degradation drive progress in hydrogen technologies.

Advances in electrochemical water conversion and understanding PEMFC degradation drive progress in hydrogen technologies.

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Are Nafion 117 containing solution and Aquivion D98-25BS are same?

    1 answer
    1. Nafion 117 and Aquivion D98-25BS are not identical. Various literature sources suggest that the major differences between Nafion and Aquivion are the different side chain lengths. However, Aquivion D98-25BS is considered to be a good alternative for Nafion™ 117.

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