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Merck

734624

Sigma-Aldrich

Cerium(IV) oxide-samarium doped

greener alternative

<0.5 μm particle size, powder, contains 20 mol % samarium as dopant

Sinónimos:

SDC-20, SDC, Samarium-doped ceria

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About This Item

Fórmula empírica (notación de Hill):
CeO2
Peso molecular:
172.11
Número MDL:
Código UNSPSC:
26111700
ID de la sustancia en PubChem:
NACRES:
NA.23

Formulario

powder

Nivel de calidad

contiene

20 mol % samarium as dopant

composición

Sm0.2Ce0.8O1.9

características de los productos alternativos más sostenibles

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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superficie

10-14 m2/g

tamaño de partícula

0.1-0.5 μm (d50)
<0.5 μm

densidad aparente

1.787 g/mL

categoría alternativa más sostenible

cadena SMILES

[Sm].O=[Ce]=O

InChI

1S/Ce.2O.Sm

Clave InChI

AQGZISMLQKBRRO-UHFFFAOYSA-N

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Descripción general

Cerium(IV) oxide-samarium doped powder (20% mol samarium doped) (SDC-20) is an electrolytic material with a high oxygen ion conductivity. Samarium ion acts as an aliovalent cation that can be incorporated into the host lattice to increase the oxygen vacancy concentration and improve the oxide ion conduction in cerium oxide. It can be synthesized by reverse strike co-precipitation technique.
Samarium doped ceria may be used as an electrolyte in solid oxide fuel cells (SOFCs). Electrical conductivity as a function of temperature of doped ceria was investigated in a study. Relation of dopant type, oxygen vacancy ordering and ionic conductivity was investigated by transmission electron microscopy and electron energy loss spectroscopy.
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Aplicación

Cerium(IV) oxide-samarium doped can be used in the fabrication of solid oxide fuel cells (SOFCs), which can further be used as environmentally-friendly sources of alternative energy.

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Samarium-doped ceria nanowires: novel synthesis and application in low-temperature solid oxide fuel Cells
Ma Y, et al.
Advanced Materials, 22(14), 1640-1644 (2010)
Effect of Gd (Sm) doping on properties of ceria electrolyte for solid oxide fuel cells,
Zha S, et al.
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We report a correlation between oxygen ionic conductivity and the enthalpy of formation of trivalent-doped ceria from the component binary oxides observed at relatively low temperatures (150-275 degrees C). The bulk conductivities of La-doped ceria samples identical to those previously

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