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Merck

517003

Sigma-Aldrich

Iron(III) acetylacetonate

≥99.9% trace metals basis

Sinónimos:

2,4-Pentanedione iron(III) derivative, Fe(acac)3, Ferric acetylacetonate, Iron(III) 2,4-pentanedionate

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About This Item

Fórmula lineal:
Fe(C5H7O2)3
Número de CAS:
Peso molecular:
353.17
Beilstein:
4157960
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
NACRES:
NA.23
En este momento no podemos mostrarle ni los precios ni la disponibilidad

Nivel de calidad

Ensayo

≥99.9% trace metals basis

Formulario

powder

idoneidad de la reacción

core: iron
reagent type: catalyst

mp

180-182 °C (dec.) (lit.)

densidad

5.24 g/mL at 25 °C (lit.)

cadena SMILES

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

Clave InChI

AQBLLJNPHDIAPN-LNTINUHCSA-K

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Descripción general

Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is an coordination compound that is used as a precursor for the synthesis of iron oxide nanoparticles and thin films, which are important in magnetic materials, catalysis, and electronic applications. Additionally, it is also used as a catalyst in various organic reactions, including polymerization processes and cross-coupling reactions.

Aplicación

Iron(III) acetylacetonate can be used as:     
  • A iron precursor for the synthesis of Fe3O4/carbon composite fibers via forcespinning technique. This composite material used in the formation of high-performance anode materials for lithium-ion batteries.      
  • A precursor for the synthesis of iron-containing metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.   
  • An additive to enhance the efficiency of the N-hydroxyphthalimide (NHPI) catalyst in the oxidation of cumene.     
  • A solvent activation agent in the fabrication of polyamide membranes, which are used in reverse osmosis (RO) applications.     
  • As a MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films. Iron (III) acetylacetonate may be used as a precursor for the synthesis of water-soluble magnetite nanoparticles, which may find applications in magnetic hyperthermia treatment.      
  • As a MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

Pictogramas

CorrosionExclamation mark

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves


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Certificados de análisis (COA)

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Visite la Librería de documentos

Studies of magnetite nanoparticles synthesized by thermal decomposition of iron (III) acetylacetonate in tri(ethylene glycol)
Maity D, et al.
Journal of magnetism and magnetic materials, 321(19), 3093-3098 (2009)
Selective Detection of Iron (III) by Rhodamine-Modified Fe3O4 Nanoparticles.
Baodui, et al.
Angewandte Chemie (International Edition in English), 49.27, 4576-4579 (2010)
Polymorphous transformations of nanometric iron (III) oxide: a review.
Zboril R, et al.
Chemistry of Materials, 23.14, 3255-3272 (2011)
Arreerat Jiamprasertboon et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(48), 11337-11345 (2019-06-27)
Type I heterojunction films of α-Fe2 O3 /ZnO are reported here as a non-titania based photocatalyst, which shows remarkable enhancement in the photocatalytic properties towards stearic acid degradation under UVA-light exposure (λ=365 nm), with a quantum efficiency of ξ=4.42±1.54×10-4 molecules degraded/photon, which
Hyun-Uk Park et al.
Ultrasonics sonochemistry, 58, 104673-104673 (2019-09-27)
In this work, we introduce composition-tunable core-shell-like PdM@Pt (M = Mn and Fe) nanoparticles (NPs) on carbon support (PdM@Pt/C) synthesized by one-pot sonochemical reactions using high-intensity ultrasonic probe (150 W, 20 kHz, with 13 mm solid probe) and investigate their electrocatalytic performance for oxygen reduction

Artículos

Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.

Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.

Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.

Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.

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Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Bonjour, nous aimerions connaître la granulométrie de l’actif (D90) de Iron(III) acetylacetonate. Merci d'avance.

    1 answer
    1. The particle size of the active ingredient is not determined.

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