469629

Poly[4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole-co-tetrafluoroethylene]

dioxole 87 mol %

• Sinónimos: PTFE AF, PTFE AF 2400 PTFE AF
• Número de CAS: 37626-13-4
• Número MDL: MFCD00803821
• Código UNSPSC: 12352103
• NACRES: NA.23

Propiedades

• descripción: contact angle 105 ° with water; critical surface energy 15.6 dyn/cm
• Nivel de calidad: 100
• composición: dioxole, 87 mol %
• constante dieléctrica: 1.904, 1 MHz (ASTM D 150)
• índice de refracción: n20/D 1.29
• solubilidad: fluorinated solvents such as perfluoromethylcyclohexane, perfluorobenzene, and perfluorodecalin: soluble
• densidad: 1.67 g/mL at 25 °C
• cadena SMILES: FC(F)(F)C1(OC(=C(O1)F)F)C(F)(F)F.FC(=C(F)F)F
• InChI: 1S/C5F8O2.C2F4/c6-1-2(7)15-3(14-1,4(8,9)10)5(11,12)13;3-1(4)2(5)6
• Clave InChI: WAQVMMYKXQPUNG-UHFFFAOYSA-N

Descripción

Descripción general

A tunable, polymeric, photonic material.

Poly(4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole-co-tetrafluoroethylene)(AF2400) is a fluorinated polymer that formed by copolymerization of 4,5-difluoro-2,2-(trifluoromethyl)-1,3-dioxole(PDD) and tetrafluoroethylene(TFE). It has a relatively high glass transition temperature(T_g) and optical transparency which allows it be a photo-stable polymer that can be used for a wide range of coating application in electronic and electrochemical industry.

Aplicación

AF2400 dissolved in supercritical CO₂ as a solvent can be used as an activated layer that forms an electrode for fuel cell applications. It may be used in the fabrication of organic nanofiltration membrane with polytetrafluoroethylene(PTFE) that can be used in the extraction of hexane from crude mixture of soybean oil. Nanocomposites of silver nanoparticles(AgNPs) may be formed by incorporating AF2400 via vapour phase co-deposition process that can be used in surface enhanced raman spectroscopy sensors and color filters.

Optically transparent due to the cycloether moieties in the structure which prevent crystallization. Also possesses nonadhesive characteristics and low refractive index making it more interesting than PTFE for optical applications.

Optoelectronic devices for optical clarity, low-refractive index coating for optical devices, protective coating for chemical resistance, release coating, and sight window for harsh chemical environments.

Used as a fluoropolymer for 157-nm lithography.

Características y beneficios

High gas permeability, high compressibility, good creep resistance, low thermal conductivity, transparent to microwaves and the lowest dielectric constant of any known fluoropolymer.

Forma física

Amorphous copolymer.

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable
• Equipo de protección personal: Eyeshields, Gloves, type N95 (US)