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448273

Sigma-Aldrich

4-Acryloylmorpholine

97%, contains 1,000 ppm monomethyl ether hydroquinone as inhibitor

Sinónimos:

1-(Morpholin-4-yl)propenone, 1-Morpholinoprop-2-en-1-one, 4-(1-Oxo-2-propenyl)morpholine, 4-Acryloylmorpholine, Acryloylmorpholine

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About This Item

Fórmula empírica (notación de Hill):
C7H11NO2
Número de CAS:
5117-12-4
Peso molecular:
141.17
Número CE:
418-140-1
Número MDL:
MFCD00047413
Código UNSPSC:
12162002
ID de la sustancia en PubChem:
24868398
NACRES:
NA.23
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Nivel de calidad

100

Ensayo

97%

contiene

1,000 ppm monomethyl ether hydroquinone as inhibitor

índice de refracción

n20/D 1.512 (lit.)

mp

−35 °C (lit.)

densidad

1.122 g/mL at 25 °C (lit.)

temp. de almacenamiento

2-8°C

cadena SMILES

C=CC(=O)N1CCOCC1

InChI

1S/C7H11NO2/c1-2-7(9)8-3-5-10-6-4-8/h2H,1,3-6H2

Clave InChI

XLPJNCYCZORXHG-UHFFFAOYSA-N

Categorías relacionadas

Descripción general

4-Acryloylmorpholine(ACMO) is an acrylate monomer widely used as a crosslinking agent in the polymer industry. It is used to form three-dimensional polymer networks to enhance the mechanical strength, stability, and durability of materials. The morpholine moiety in acryloylmorpholine imparts hydrophilicity to the molecule facilitating its applications in the field of adhesives, biocompatible coatings, and drug delivery systems. It is also used as a reactive monomer to synthesize hydrogels for drug delivery, photocurable materials for 3D bioprinting and display devices.[1] [2]

Aplicación

4-Acryloylmorpholine can be used as a monomer:
  • To synthesize multiblock copolymers via RAFT polymerization. These functional block copolymers find application in the fields of medicine, energy, and nanotechnology.[3]
  • To prepare organogel electrode frame via photopolymerization and cross-linking. This can be used to fabricate triboelectric nanogenerators with excellent transparency, stretchability, and interface adhesion.[1]
  • For printing thermoplastic 3D tissue scaffolds. ACMO′s water solubility,and remarkably low viscosity, combined with surface oxygen inhibition, promoteswift liquid flow during high-speed open-air printing.[2]

Palabra de señalización

Danger

Frases de peligro

H302,H317,H318,H373

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Oral

Código de clase de almacenamiento

10 - Combustible liquids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

259.7 °F - closed cup

Punto de inflamabilidad (°C)

126.5 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
MKCW4883
MKCW3560
MKCW9946
MKCW9829
MKCT1970

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Organ gel electrode enables highly transparent and stretchable triboelectric nanogenerators of high power density for robust and reliable energy harvesting
Titao Jing, et al.
Nano Energy, 78, 105373-105373 (2020)
Rapid open-air digital light 3D printing of thermoplastic polymer
Shihong Deng, et al.
Advanced Materials, 31, 1903970-1903970 (2019)
Ultrafast RAFT polymerization: multiblock copolymers within minutes
Guillaume Gody, et al.
Polymer Chemistry: Introduction to an Indispensable Science, 6, 1502-1511 (2015)
Hafiz Awais Nawaz et al.
Journal of materials chemistry. B, 9(9), 2295-2307 (2021-02-23)
Injectable gelatine-based hydrogels are valuable tools for drug and cell delivery due to their extracellular matrix-like properties that can be adjusted by the degree of cross-linking. We have established anhydride-containing oligomers for the cross-linking of gelatine via anhydride-amine-conjugation. So far
Kalyan Ramesh et al.
Materials (Basel, Switzerland), 13(17) (2020-08-28)
Owing to their unique topology and physical properties, micelles based on miktoarm amphiphilic star block copolymers play an important role in the biomedical field for drug delivery. Herein, we developed a series of AB2-type poly(D,L-lactide-co-glycolide)-b-poly(N-acryloyl morpholine) (PLGA-b-PNAM2) miktoarm star block
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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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