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The purity of this item is not tested for this item. The percentage of Chloride and Bromide is not on the COA and not tested for.
339768
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate
Sinónimos:
NSC 307191, Palladium(II) tetrafluoroborate tetraacetonitrile complex
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About This Item
Fórmula lineal:
Pd(CH3CN)4(BF4)2
Número de CAS:
Peso molecular:
444.24
Número MDL:
Código UNSPSC:
12161600
ID de la sustancia en PubChem:
NACRES:
NA.22
En este momento no podemos mostrarle ni los precios ni la disponibilidad
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Formulario
solid
Nivel de calidad
idoneidad de la reacción
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
reagent type: ligand
mp
230 °C (dec.) (lit.)
cadena SMILES
[Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F
InChI
1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2
Clave InChI
YWMRPVUMBTVUEX-UHFFFAOYSA-N
Descripción general
Aplicación
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Reactant involved in:
Precursor for:
Reactant involved in:
- Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands
Precursor for:
- Synthesis of dendritic SCS-pincer palladium complexes
- Palladium complexes of click ligands
- Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination
Palabra de señalización
Warning
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Acute Tox. 4 Inhalation
Código de clase de almacenamiento
11 - Combustible Solids
Clase de riesgo para el agua (WGK)
WGK 3
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
Equipo de protección personal
dust mask type N95 (US), Eyeshields, Gloves
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Extended-chain complexes containing multiple transition metal centres linked by conjugated micro-cyanodiazenido(1-) ligands [N=N-C[triple bond, length as m-dash]N]- have been obtained by reaction of trans-[BrW(dppe)2(N2CN)], , [dppe=1,2-bis(diphenylphosphino)ethane] with dirhodium(II) tetra-acetate, bis(benzonitrile)palladium(II) dichloride, and bis(aqua)M(II) bis(hexafluoroacetylacetonate) (M=Mn, Ni, Cu, Zn): stronger Lewis
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Structurally diverse beta-hydroxyenones are shown to undergo nonoxidative 6-endo-trig ring closure to form highly substituted tetrahydropyranones. Amberlyst-15, Al(ClO(4))(3) x 9 H(2)O and [Pd(MeCN)(4)](BF(4))(2) were found to be suitable catalysts for these intramolecular conjugate additions, preventing side reactions, such as dehydration
Unique 2:1 complex with a trans-chelating bis-pyridine ligand.
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