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Merck

334545

Sigma-Aldrich

Potassium gold(III) chloride

98%

Sinónimos:

Potassium tetrachloroaurate(III), Gold potassium chloride

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About This Item

Fórmula lineal:
KAuCl4
Número de CAS:
Peso molecular:
377.88
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

98%

form

powder

solubility

H2O: soluble
alcohol: soluble
ethanol: soluble

SMILES string

[K+].Cl[Au-](Cl)(Cl)Cl

InChI

1S/Au.4ClH.K/h;4*1H;/q+3;;;;;+1/p-4

InChI key

JMONCQYBAMKVQQ-UHFFFAOYSA-J

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General description

The yellow crystals of potassium gold chloride are soluble in water. 1,2

Application

Key raw material for synthesis of new gold(III) dithiolate complexes for luminescence studies or possible uses as photosensitizers or photocatalysts.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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M. Adnan Mansour et al.
Inorganic chemistry, 37(18), 4625-4632 (2001-10-24)
Two Au(III) dithiolate complexes, [Au(dbbpy)(tdt)]PF(6) and Au(eta(2)-C,N-ppy)(tdt), (dbbpy = 4,4'-di-tert-butyl-2,2'-bipyridine; tdt = 3,4-toluenedithiolate; ppy = C-deprotonated 2-phenylpyridine), have been prepared and structurally characterized by X-ray crystallography. The complexes have low-energy absorption bands that exhibit mild solvatochromism (lambda(max) = 444 nm
Andrew R Garcia et al.
Colloids and surfaces. B, Biointerfaces, 105, 167-172 (2013-02-05)
Fluorescent insulin fibrils gold nanoclusters (Au NCs) have been synthesized through the reduction of gold by human insulin in fibrillated form. Likewise, nanocluster formation has been regulated by insulin, working as a protein-based template. Environment- and surface-controlled experiments have shown
S Veeraapandian et al.
Journal of biomedical nanotechnology, 8(1), 140-148 (2012-04-21)
Escherichia coli is used for eco-friendly extra cellular synthesis of metallic silver and gold nanoparticles. This is achieved by reducing AgNO3 and HAuCl4 solutions respectively under ambient conditions by using the extra cellular protein produced by the microorganism. The proteins
Xiaokong Liu et al.
Langmuir : the ACS journal of surfaces and colloids, 28(38), 13720-13726 (2012-09-08)
In this report, we demonstrate a rapid and simple seeded growth method for synthesizing monodisperse, quasi-spherical, citrate-stabilized Au nanoparticles (Au NPs) via H(2)O(2) reduction of HAuCl(4). Au NPs with diameter ranging from 30 to 230 nm can be synthesized by
Sergey S Zalesskiy et al.
Journal of the American Chemical Society, 135(9), 3550-3559 (2013-01-02)
Soluble gold precatalysts, aimed for homogeneous catalysis, under certain conditions may form nanoparticles, which dramatically change the mechanism and initiate different chemistry. The present study addresses the question of designing gold catalysts, taking into account possible interconversions and contamination at

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