267112
Palladium
wire, diam. 1.0 mm, 99.9% trace metals basis
Sinónimos:
Palladium (powder), Palladium black, Palladium element
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About This Item
Fórmula lineal:
Pd
Número de CAS:
Peso molecular:
106.42
Número CE:
Número MDL:
Código UNSPSC:
12141733
ID de la sustancia en PubChem:
NACRES:
NA.23
Productos recomendados
Nivel de calidad
Ensayo
99.9% trace metals basis
Formulario
wire
resistividad
9.96 μΩ-cm, 20°C
Diámetro
1.0 mm
bp
2970 °C (lit.)
mp
1554 °C (lit.)
densidad
12.02 g/cm3 (lit.)
cadena SMILES
[Pd]
InChI
1S/Pd
Clave InChI
KDLHZDBZIXYQEI-UHFFFAOYSA-N
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Aplicación
Palladium is widely used as a metal wire electrode to synthesize Pd-based nanomaterials with good electrocatalytic activity. For example, it is used to prepare carbon-supported Pd nanoclusters and PdAu nanoparticles.
Itcan also be used as a hydrogenation catalyst in various organic reactions, suchas hydrogenation of alkenes and alkynes to their corresponding hydrocarbons.
Itcan also be used as a hydrogenation catalyst in various organic reactions, suchas hydrogenation of alkenes and alkynes to their corresponding hydrocarbons.
Cantidad
900 mg = 10 cm; 9 g = 100 cm
Código de clase de almacenamiento
13 - Non Combustible Solids
Clase de riesgo para el agua (WGK)
WGK 3
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
Equipo de protección personal
Eyeshields, Gloves, type N95 (US)
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Stefano Nicolai et al.
The Journal of organic chemistry, 78(8), 3783-3801 (2013-03-21)
Tetrahydrofurans and pyrrolidines are among the most important heterocycles found in bioactive compounds. Cyclization-functionalization domino reactions of alcohols or amines onto olefins constitute one of the most efficient methods to access them. In this context, oxy- and aminoalkynylation are especially
Meifang Zheng et al.
Organic letters, 15(8), 1838-1841 (2013-04-02)
Palladium-catalyzed oxidative difunctionalization of enol ethers with 1,3-dicarbonyl compounds to construct trisubstituted furans in one step under mild conditions is described. The reaction is thought to proceed through a C-C bond formation along with a C-O bond closing the ring
Xuxing Chen et al.
Organic & biomolecular chemistry, 11(16), 2582-2585 (2013-03-19)
A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.
On the role of surface diffusion in determining the shape or morphology of noble-metal nanocrystals.
Xiaohu Xia et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(17), 6669-6673 (2013-04-10)
Controlling the shape or morphology of metal nanocrystals is central to the realization of their many applications in catalysis, plasmonics, and electronics. In one of the approaches, the metal nanocrystals are grown from seeds of certain crystallinity through the addition
Ling Li et al.
Nature chemistry, 5(7), 607-612 (2013-06-22)
The development of transition metal-catalysed cross-coupling reactions has greatly influenced the manner in which the synthesis of complex organic molecules is approached. A wide variety of methods are now available for the formation of C(sp(2))-C(sp(2)) bonds, and more recent work
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