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197637

Sigma-Aldrich

Imidazole sodium derivative

technical grade

Sinónimos:

Imidazolylsodium, Sodium imidazolide

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About This Item

Fórmula empírica (notación de Hill):
C3H3N2Na
Número de CAS:
5587-42-8
Peso molecular:
90.06
Beilstein/REAXYS Number:
3569312
EC Number:
226-988-5
MDL number:
MFCD00064314
UNSPSC Code:
12352005
eCl@ss:
39161001
PubChem Substance ID:
24851839
NACRES:
NA.22

grade

technical grade

mp

284 °C (dec.) (lit.)

SMILES string

[Na]n1ccnc1

InChI

1S/C3H3N2.Na/c1-2-5-3-4-1;/h1-3H;/q-1;+1

InChI key

ITAWMPSVROAMOE-UHFFFAOYSA-N

Application

Imidazole sodium derivative (Imidazolylsodium) was used in the synthesis of arylazidoamorphigenin.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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F G Earley et al.
The Biochemical journal, 224(2), 525-534 (1984-12-01)
A photoaffinity-labelling analogue of the respiratory inhibitor rotenone was synthesized from the naturally occurring rotenoid amorphigenin. The analogue inhibits NADH-ubiquinone oxidoreductase activity at concentrations comparable with those of rotenone. Photolysis of the radiolabelled analogue bound to isolated NADH-ubiquinone oxidoreductase resulted
Sun Un
Inorganic chemistry, 52(7), 3803-3813 (2013-03-21)
A common feature of a large majority of the manganese metalloenzymes, as well as many synthetic biomimetic complexes, is the bonding between the manganese ion and imidazoles. This interaction was studied by examining the nature and structure of manganese(II) imidazole
Haiying Li et al.
Physical chemistry chemical physics : PCCP, 15(12), 4405-4414 (2013-02-20)
In recent years, several specific imidazolium-based ionic liquids with halogen substituents on the imidazole ring as well as on the alkyl chains have been reported. In this work, noncovalent interactions in four halogenated ionic liquids, i.e. 2-bromo-/iodo- and 4,5-dibromo-/diiodo-1,3-dimethylimidazolium trifluoromethanesulfonates
Ho Young Lee et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(14), 5416-5421 (2013-03-16)
RNA-binding proteins control the fate and function of the transcriptome in all cells. Here we present technology for isolating RNA-protein partners efficiently and accurately using an engineered clustered regularly interspaced short palindromic repeats (CRISPR) endoribonuclease. An inactive version of the
Chuanjiang Hu et al.
Inorganic chemistry, 52(6), 3170-3177 (2013-03-09)
The effects of the deprotonation of coordinated imidazole on the vibrational dynamics of five-coordinate high-spin iron(II) porphyrinates have been investigated using nuclear resonance vibrational spectroscopy. Two complexes have been studied in detail with both powder and oriented single-crystal measurements. Changes
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